Tetrahydrofuran, One of the Most Popular Solvents in Organic Synthesis, Is Not Completely Inert

• Autorzy: Makowiec S. , Rachon J.
• Języki publikacji: EN

Abstrakty

EN

Tetrahydrofuran undergoes fast ring cleavage in the reaction with PhI(OH)OTs/(RO)2P(O)H system, which causes the formation of O-(dialkoxyphosphoryl)-O_-tosyl-1,4-butanediol. This fact indicates that tetrahydrofuran is not suitable as a solvent for reactions with strong electrophilic reagents, such as hypervalent iodine reagents.

Słowa kluczowe

EN

diisopropylphosphite; tetrahydrofuran; Koser's reagent

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 3
• Strony: 487--492
• Opis fizyczny: Bibliogr. poz. 15, rys.

Twórcy

autor

Makowiec S.

• Department of Organic Chemistry, Faculty of Chemistry, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk, Poland

autor

Rachon J.

• Department of Organic Chemistry, Faculty of Chemistry, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk, Poland

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