Spectrochemical Properties of Noncubic Transition Metal Complexes in Solution : XI. Angular Overlap Studies of Bis(oxalato)- and Bis(malonato)diaquachromate(III) Complexes in Aqueous Solution

• Autorzy: Kurzak K.
• Języki publikacji: EN

Abstrakty

EN

Mixed ligands chromium(III) complexes with monodentate(water) and bidentate ligands: oxalic acid deprotonated or malonic acid have been synthesized, investigated and characterized structurally and spectroscopically. Their geometrical isomers have been studied spectrophotometrically in aqueous solution. The "poor" experimental contours were resolved into the component bands by Gaussian analysis.The effect of different bonding of the bidentate ligands upon the chromium(III) ion in aqueous solution was described and discussed.

Słowa kluczowe

EN

angular overlap model; chromium(III); dicarboxylic acids; electronic spectra; geometrical isomers; molecular structure; solutions

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2000
• Tom: Vol. 74, nr 3
• Strony: 331--347

Twórcy

autor

Kurzak K.

• Department of Chemistry University of Podlasie PL 08-110 Siedlce, Poland