Spectroscopic and Thermal Studies of Silver(I) Complexes with Aliphatic Carboxylates and Triphenylphosphine

• Autorzy: Szłyk E. , Łakomska I. , Surdykowski A. , Goliński A.
• Języki publikacji: EN

Abstrakty

EN

Results of spectral analysis are in favour of Ag(I) trigonal coordination with unidentately bonded triphenylphosphine and bidentate carboxylates, forming bridges between silver(I) ions. Thermal decomposition was studied in 293-973 K range in nitrogen. The multistage decomposition initiates with the detachment of carboxylates and is followed by triphenylphosphine dissociation. The final product is metallic silver, formed between 605-683 K.

Słowa kluczowe

EN

Ag(I) complexes; triphenylphosphine; aliphatic; aliphatic carboxylates; thermal analysis; IR; NMR

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1999
• Tom: Vol. 73, nr 11
• Strony: 1763--1769

Twórcy

autor

Szłyk E.

autor

Łakomska I.

autor

Surdykowski A.

autor

Goliński A.

• Uniwersytet Mikołaja Kopernika Wydzial Chemii 87-1000 Toruń