Cation of N-Allylbenzothiazolium as a P-Ligand in Copper(I) Halide Complexes: Synthesis and Crystal Structure of [C7H5NS(C3H5)]+.CuCIcl2.H2O and [C7H5NS(C3H5)]+.CuCl1.06Br0.94.H2O Compunds

• Autorzy: Goreshnik E. , Mys'kiv M.
• Języki publikacji: EN

Abstrakty

EN

By alternating-current electrochemical synthesis crystals of [ ] P-complexes have been obtained and structurally characterized. Owing to the cationic form, the ligand is coordinated to Cu atom only through the C=C bond. Due to the bridge role of X(2) atom [X=Cl(I) or statistic mixture Cl, Br (II))}, cyclic fragments Cu2X2 appear.

Słowa kluczowe

EN

copper(I); P-complexes; X-ray structure; N-allylbenzothiazolium cation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1999
• Tom: Vol. 73, nr 8
• Strony: 1245--1252

Twórcy

autor

Goreshnik E.

autor

Mys'kiv M.