Synthesis of modified oligosaccharide derivatives by Ferrier rearrangement

• Autorzy: Wieczorek E. , Thiem J.
• Języki publikacji: EN

Abstrakty

EN

Various glycols of the hexose and pentose series and different dideoxy hexopyranosides undergo smooth (Lewis) acid -catalyzed allylic rearrangement reactions to regioisometric deoxygenated disaccharide derivatives. The corresponding saturated components were obtained by hydrogenation. In addition, yhe neutral version of the Ferrier reaction employing pentenoyl glucal was tested, which gave rearrangement and addition products. Finally, certain glycols were condensed with differently functionalized glycols as aglyconic components to form disaccharide glycals.

Słowa kluczowe

EN

glycals; Ferrier reaction; deoxy oligosaccharides

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 1999
• Tom: vol. 73 nr 7
• Strony: 1111--1121

Twórcy

autor

Wieczorek E.

autor

Thiem J.