Tytuł artykułu
Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
Bis(ethylammonium) pentachloroantimonate(III)-ethylamonium chloride belongs to alkylammonium chloroantimonates(III). The anionic sublattice of (C2H5NH3)2SbCl5 × (C2H5NH3)cl is built of isolated Sb2Cl10 4- units composed of two SbCl-36 octahedra, connected by edge and two single chlorine Cl- ions. There are three crystallographically non-equivalent ethylammonium cations, two of them are disordered at room temperature and all of them are ordered at 90 K. The disorder is realized by two positions for carbon atoms. Ethylammonium cations are connected to the anionic sublattice by N-H…Cl hydrogen bonds. The influence of temperature and hydrogen bonds together with electrostatic interactions on the deformation of the octahedral coordination of SbIII is discussed.
Wydawca
Czasopismo
Rocznik
Tom
Strony
773--782
Opis fizyczny
Twórcy
Bibliografia
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ2-0002-0045