Phase Equilibria in the Cu2S-{Sb,Bi}2S3-Ga2S3 and Cu2S-{Sb,Bi}2S3-In2S3 Systems at 673 K

• Autorzy: Olekseyuk I. , Zhbankov O. , Kumanska Y. , Tkachuk V.
• Języki publikacji: EN

Abstrakty

EN

Phase equilibria in the Cu2S-{Sb,Bi}2S3-Ga2S3 and Cu2S-{Sb,Bi}2S3-In2S3 systems at 673 K were investigated by X-ray powder diffraction and their isothermal sections were constructed. No quaternary compounds or continuous solid solutions were found. The homogeneity region of the CuIn5S8 phase in quasibinary Cu2S-In2S3 system was determined in the range 7.3-17.2mol.% Cu2S. The Rietveld refinement of the crystal structure CuGa5S8 has been performed, using powder diffraction pattern in the zinc blende model (SG F43m, a = 0.52246(2) nm).

Słowa kluczowe

EN

phase diagram; solid solution; lattice parameters; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2006
• Tom: Vol. 80, nr 5
• Strony: 817--823
• Opis fizyczny: Bibliogr. 29 poz.

Twórcy

autor

Olekseyuk I.

autor

Zhbankov O.

autor

Kumanska Y.

autor

Tkachuk V.

• Department of General and Inorganic Chemistry, Volyn' State University, Voli. ave. 13, Lutsk, 43009, Ukraine

Bibliografia

• 1. Konovalov I., Thin Sol. Films, 451-452, 413 (2004).
• 2. Rogacheva E.I., Cryst. Res. Technol, 31, l (1996).
• 3. Sashital S.R. and Gentile A.L., J. Cryst. Growth, 69, 379 (1984).
• 4. Matsushita H., Katsui A. and Takizawa T., J. Cryst. Growth, 237-239, 1986 (2002).
• 5. Chaus I.S., Kompanichenko N.M., Andreitchenko V.G. and Gornikov Yu.L, Ukr. Khim. J., 53, 465 (1987).
• 6. Abrahams S.C. and Bernstein J.L, J. Chem. Phys., 59, 5415 (1973).
• 7. Belova Ye.K., Koshkin V.M. and Palatnik A.S., Inorg. Mater., 3, 617 (1967).
• 8. Binsma J.J., Giling L.J. and Bloem J., J. Cryst. Growth, 50, 429 (1980).
• 9. Brandt G., Raeuber A. and Schneider J., Solid State Commun., 12, 481 (1973).
• 10. Gastaldi L. and Scaramuzza L., Acta Crystallogr., B36, 2751 (1980).
• 11. Ohachi T. and Pamlin B.M., J. Cryst. Growth, 42, 598 (1977).
• 12. Bwndzia L.T. and Davis A.M., J. Am. Mineral, 74, 236 (1989).
• 13. Pfitzner A., Z. Anorg. Allg. Chem., 620, 1992 (1994).
• 14. Hoffmann W., Z. Kristalhgr. Kristallgeom. Kristallphys. Kristallchem., A84, 177 (1933).
• 15. Mohtabzade A.Z., Doctoral thesis. Baku 1992.
• 16. Kocman V. and Nuffield E.W., Acta Crystallogr., 29, 2528 (1973).
• 17 Ozawa T. and Novacki W., Z. Kristalhgr. Kristallgeom. Kristallphys. Kristallchem., 142, 161 (1975).
• 18. Mariolacos K., Kupcik V., Ohmasa M. and Miehh G., Acta Cryst., B31, 703 (1975).
• 19. Liautard B., Garcia J.C., Brun G., Tedenac J.C. and Maurin M., Eur. J. Solid State and Inorg. Chem., 27,819(1990).
• 20  OhmasaM. andNowackiW.,Z. Kristalhgr. Kristallgeom. Kristallphys. Kristallchem., 137,422(1973).
• 21. Kompanichenko N.M., Chaus I.S. and Suhenko V.R, J. Inorg. Chem., 18, 1080 (1973).
• 22. Laminsi S., Kom J.K., Fues H. and Paulus H., Afr. J. Science Technol, Sci. Engin. Ser., 4, 39 (2003).
• 23. Kramer V., Thermochim. Acta, 15, 205 (1976).
• 24. Kramer V., Thermochim. Acta, 86, 291 (1985).
• 25. Chapuis G. and Gnehm C., Acta Crystallogr., B28, 3128 (1972).
• 26. Guittard M., Pardo M.P. and Ecrepont C., C.R. Acad. Sci. Paris, 307, 141 (1988).
• 27. Kraus W. and Nolze G., J. Appl Cryst., 29, 301 (1996).
• 28. Axelrud L.G., Grin' Yu.N., Zavalij P.Yu., Pecharsky V.K. and Fundamentsky V.S., in: Collected Abstracts of the 12th European Crystallographic Meeting, Moscow, August, 1989, Izv. Acad. Nauk 555/2,3,155(1989).
• 29. Yang Y, Brazis P., Kannewurf C.R. and Ibers J.A., J. Solid State Chem., 155, 243 (2000).