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Octasilsesquioxanes as Hybrid Nanocomposite Platforms. II. Synthesis, Characterization and Properties of Some Alkyl-functionalized Sislesquioxanes

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The syntheses of octaalkylsilsesquioxanes 3, 4, 5 and 6 have been achieved by the platinum- catalyzed hydrosilylation of octahydrogensilsesquioxane 2 with _-halo-alkenes and other unsaturated substrates. These compounds were characterized by spectroscopic techniques and elemental analysis. Thermogravimetric analyses of 3 and 4 shows that they are reasonably stable thermally, and may act as building blocks to ceramics, nanometer ball bearing at around 400°C and photoresist materials.
Rocznik
Strony
101--107
Opis fizyczny
Bibliogr. 25 poz., rys.
Twórcy
autor
  • Department of Chemistry, University of Agriculture, P. O. Box 28,UNAAB post office, Abeokuta, Nigeria
autor
  • Department of Chemistry, University of Ilorin, P. M. B 1515, Ilorin, Nigeria
autor
  • Department of Chemistry, University of Ilorin, P. M. B 1515, Ilorin, Nigeria
Bibliografia
  • 1.Voronkov M.G. and Lavrent’yev V.l., Top. Cum Chem., 102, 199 (1982).
  • 2.Kung H.H. and K0 E.I., Chem. Eng. J., 64, 203 (1996)
  • 3.Harrison P.G. and Kannengiesser R., Chem. Comm., 415 (1996)
  • 4. Hoebbel K., Endres K., Reinert T. and Pitsh J., .J. Non-cryst. Solids, 176, 179 (1994).
  • 5. Feher F.J. and Budzichowski T.A., Polyhedron, 14, 3239 (1995).
  • 6. Edelmann F.T., Angew. Chem., 104, 600 (1992); Angew. Chem. Int. Ed. EngI., 31, 586 (1992).
  • 7. Frye C.L. and Collins W.T., J. Am. Chem. Soc., 5586 (1970).
  • 8. Tosaka H., Yamaguchi K., Orihara M., Ide N. and Otaki K., Jap. Patent 8724,268; C.A., 107, 124570 (1987)
  • 9. Agaskar P.A., Day V.W. and Klemperer W.G., .J. Am. Chem. Soc., 109, 5554 (1987).
  • 10. Fyfe C.A. and Fu G., J. Am. Chem. Soc., 117, 9709 (1995).
  • 11.Firouzi A., Kumar D., Bull L.M., Besier T., Sieger P., Huo Q. Walker S.A., Glinker C., Nikol J., Margolese D., Stucky G.D. and Chmelka B.F., Science, 267, 1138 (1995).
  • 12. Dare E.O., Olatunji G.A. and Ogunniyi D.S., J. Appl. Polym. Sci., 93, 907 (2004).
  • 13.Agaskar P.A., Inorg. Chem., 30, 2707 (1991).
  • 14. Herren D., Burgy H. and Calzaferri G., Helv. Chim. Acta., 71, 24 (1991).
  • 15. Chalk A.J. and Harrod J.F., .I. Am. Chem. Soc., 89, 16 (1965)
  • 16. Tsuchida A., Bolln C., Semetz F.G., Frey H.. and Mulhaupt R., Macromolecules, 30, 2818 (1997).
  • 17. Bassindale A.R. and Gentle T.E., .I. Mater: Chem., 3, 1319 (1993).
  • 18. Feher F.J. and Wyndham K.D., Chem. Commun, 323 (1998).
  • 19. Said M.A., Roesky H.W. and Rennekamp C., Angew. Chem. Int. Ed., 38, 661 (1990).
  • 20. Babonneau F., Thome K. and Mackenzie J.D., Chem. Man, 1, 554 (1989).
  • 21. Zhang H. and Pantano C.G., J. Am. Ceram. Soc., 73, 958, (1990).
  • 22. Rappoport Z. and Apeloig Y., The Chemistry of Organic Silicon Compounds; Wiley: NY 1998, vol. 2, p. 1479.
  • 23.Belot V., Corriu R.J.P., Leclercq D., Mutin RH. and Vioux, .J. Polym. Sc. Part A: Polym. Chem., 30, 613 (1992).
  • 24. Laine R.M. and Sellinger A., in Silicon-based Polymer; Wiley NY 1990, p. 2294.
  • 25. Chunxin Z. and Laine R.M., J Am. Chem. Soc., 122, 6979 (2000).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0025-0099
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