New Reactions of Thiocyanatobismuthates(III) with Organic Compounds. II. Reactions of Tetrathiocyanatobimuthates(III) with Monocarboxylic Acids Salts Containing an Aromatic Ring

Cichecka, M.; Cygański, A.

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Tytuł artykułu

New Reactions of Thiocyanatobismuthates(III) with Organic Compounds. II. Reactions of Tetrathiocyanatobimuthates(III) with Monocarboxylic Acids Salts Containing an Aromatic Ring

Autorzy

Cichecka M. , Cygański A.

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Warianty tytułu

Języki publikacji

Abstrakty

Our previous work [1] presented the reactions of caesium tetrathiocyanatobismuthate( III) with the solutions of sodium salts in aliphatic monocarboxylic acids. In this study the still unreported reactions of Cs[Bi(SCN)4] with solutions of sodium benzoate, salicylate and anthranilate, and those of Rb[Bi(SCN)4] with sodium salicylate solution are treated. The chemical, XRD, IR and thermal analyses of the reaction products were carried out. The composition of the product depends on the type of the ligand. In the case of benzoate in the solid phase, only one complex compound, Cs2Na[Bi(SCN)6] is formed, whereas the salicylate and anthranilate form two complex bismuth compounds, Cs2Na[Bi(SCN)6] and BiX3 (X - a salicylate or anthranilate anion) or BiX3.NaX.

Słowa kluczowe

Bi(III) complexes synthesis biological activity compounds carboxylic acid salts X-ray analysis IR spectra thermal decomposition

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2004

Tom

Vol.78 /nr 11-12

Strony

2037--2045

Opis fizyczny

Bibliogr. 23 poz., rys.

Twórcy

autor

Cichecka M.

Institute of General and Ecological Chemistry, Technical University of Łódź,Żeromskiego 116, 90-924,Łódź, Poland

autor

Cygański A.

Institute of General and Ecological Chemistry, Technical University of Łódź,Żeromskiego 116, 90-924,Łódź, Poland

Bibliografia

1. Cichecka M. and Cygański A., Polish J. Chem., 77, 1723 (2003).
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21. Unpublished results.
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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0024-0140