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Abstrakty
Undoped andW-doped polycrystalline TiO2 were investigated. The kinetics of recombination processes has been studied. The flat band potential of TiO2 was determined (-0.11 V in respect to saturated calomel electrode, at pH = 7.8). Basing on the photocurrent experiments, the effect of Wconcentration on solar energy conversion efficiency was discussed. It was found, that addition ofWleads to an increase of solar-to-hydrogen energy efficiency. The maximum energy conversion efficiency has been observed for voltage bias ca 0.65 V. The highest energy conversion efficiency has been observed for TiO2 doped with 0.1 at % W.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
1925--1934
Opis fizyczny
Bibliogr. 30 poz., rys.
Twórcy
autor
- AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. Mickiewicza 30, 30-059 Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
- 1. Fujishima A. and Honda K., Nature, 238, 37 (1972).
- 2. Ghosh A.K. and Maruska H.P., J. Electrochem. Soc., 124, 1516 (1977).
- 3. Juliao J.F., Decker F. and Abramovich R.M., J. Electrochem. Soc., 127, 2264 (1980).
- 4. Akikusa J. and Khan S.U.M., Int. J. Hydrogen Energy, 22, 875 (1997).
- 5. Gautron J., Lemasson P. and Marucco J.F., Faraday Disc., 70, 81 (1980).
- 6. Kogan Ya.L. and Vakulenko A.M., Solar Energy Mater., 3, 357 (1980).
- 7. Matsumoto Y., Kurimoto J., Amagasaki Y. and Sato E., J. Electrochem. Soc., 127,2148 (1980).
- 8. Bak T., Nowotny J., Rekas M. and Sorell C.C., Int. J. Hydrogen Energy, 27, 19 (2002).
- 9. Matsumoto Y., Kurimoto J., SchimizuT. and Sato E, J. Electrochem. Soc., 128, 1040 (1981).
- 10. Monnier A. and Augustynski J., J. Electrochem. Soc., 127,1576 (1980).
- 11. Giordano N., Antonucci V., Cavallaro S., Lembo R. and Bart J.CJ., Int. J. Hydrogen Energy, 7, 867 (1982).
- 12. Di Quatro F., Piazza S. and Sunseri C., Electrochim. Acta, 38, 29 (1993).
- 13. Radecka M., Wierzbicka M. and Rekas M., Physica C, in print.
- 14. Bak T., Nowotny J., Rekas M. and Sorrell C.C., Int. J. Hydrogen Energy, 27, 991 (2002).
- 15. Grant F.A., Rev. Modern Phys. ,31, 647 (1959).
- 16. Salvador P., Solar Energy Mater., 2, 413 (1980).
- 17. Madou M.J., Kinoshita K. and McKubre M.C.H., Electrochim. Acta, 29, 419 (1984).
- 18. Wrighton M.S., Ellis A.B., Wólczański P.T., Morse D.L., Abrahamson H.B. and Ginley D.S., J. Am. Chem. Soc., 98, 2774 (1976).
- 19. Gennari F.C. and Pasquievich D.M., J. Am. Ceram. Soc., 82, 1915 (1999).
- 20. Gajerski R., Radecka M., Wierzbicka M. and Rekas M., J. Therm. Anal. Calorim., 76, 949 (2004).
- 21. Radecka M., Wierzbicka M., Komornicki S. and Rekas M., Physica B, 348, 160 (2004).
- 22. Tafalla D., Salvador P. and Benito R.M., J. Electrochem. Soc., 137, 1810 (1990).
- 23. Hagfeldt A., Lindstrom H., Sodergren S. and Lindquist S.E., J. Electroanal. Chem., 381, 39 (1995).
- 24. CRC Handbook of Chemistry and Physics, CRC Press Inc., 60th edition p. D156.
- 25. Bak T., Nowotny J., Rekas M. and Sorcell C.C., J. Phys. Chem. Solid, 64, 1043 (2003).
- 26. Butler M.A., Abramovich A., Decker F. and Juliao J.F., J. Electrochem. Soc., 122, 200 (1981).
- 27. Finklea H.O., Semiconductor electrodes, Finklea H.O, Ed., Elsevier Sci. Publ., NY 1988, pp. 115-119.
- 28. Pleskov Yu.V. and Gurevich Yu.Ya., Semiconductor Photoelectrochemistry, Bartlett P.N. (Translation Ed.). Consultants Bureau NY, London 1986, pp. 179-208.
- 29. Gerischer J., Solar energy conversion, Seraphin B.O., Ed., Springer, Berlin, 1979 pp. 115-172.
- 30. Parkinson B., Acc. Chem. Res., 17, 431 (1984).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0024-0128