Contribution of Electrochemistry to the Knowledge on structure and Properties of Amalgams

Gumiński, C.

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Tytuł artykułu

Contribution of Electrochemistry to the Knowledge on structure and Properties of Amalgams

Autorzy

Gumiński C.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The most contemporary shapes of the binary phase diagrams of mercury with all elements are displayed in an integral form. Such presentation allows to follow changes of the phase diagram boundaries in the groups and periods of the periodic table of elements. Selection of the critically assessed solubilities of elements is given in a tabular form. Formation of intermetallic compounds, when two metals are introduced into mercury, is briefly characterized. Our knowledge on these fields of interest was considerably extended by the use of various electrochemical techniques. Diffusion coefficients of metals in mercury are mainly determined by electrochemical methods. An analysis of the diffusion data contributes with important informations about structure of simple amalgams; these conclusions are confirmed by other physico-chemical measurements. A liner dependence is observed between logarithms of the standard rate constants of discharging of aquo-ions on mercury electrode and the metal solubilities in mercury.

Słowa kluczowe

mercury binary phase diagrams solubilities of elements in mercury reactions and equilibria in complex amalgams diffusion coefficients of metals in mercury kinetics of discharge of metal ions on mercury electrode

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2004

Tom

Vol. 78 / nr 9

Strony

1733--1751

Opis fizyczny

Bibliogr. 112 poz., rys.

Twórcy

autor

Gumiński C.

Laboratory of Chemical Electroanalysis, Department of Chemistry,University of Warsaw, Pasteura 1, 02-093 Warszawa, Poland

Bibliografia

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13. Gumiński C., J. Phase Equil., 14, 90 (1993).
14. Gumiński C., to be published.
15. Gumiński C., J. Phase Equil., 21, 173 (2000).
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18. Gumiński C„ ibid., 14, 391 (1993).
19. Gumihski C„ ibid., 16, 277 (1995).
20. Gumiński C„ ibid., 14, 382 (1993).
21. Gumiński C„ ibid., 16, 454 (1995).
22. Gumiński C„ ibid., 16, 448 (1995).
23. Gumiński C., ibid., 16, 526 (1995).
24. Gumiński C., ibid., 16, 86 (1995).
25. Gumiński C„ ibid., 14, 97 (1993).
26. Gumiftski C., ibid., 16, 181 (1995).
27. Gumiński C„ ibid., 16, 193 (1995).
28. Gumiński C., ibid., 16, 73 (1995).
29. GumiAski C., ibid., 16, 77 (1995).
30. Gumirtski C., ibid., 16,177 (1995).
31. Gumiński C„ ibid., 16,459 (1995).
32. Gumiński C„ ibid., 16, 348 (1995).
33. Gumiński C., ibid., 16, 276 (1995).
34. Gumiński C., ibid., 16, 332 (1995).
35. Gumiński C., ibid., 15, 204 (1994).
36. Gumiński C., to be published.
37. Gumiński C., J. Phase Equil., 24, 461 (2003).
38. Gumiński C., ibid., 20, 84 (1999).
39. Gumiński C., to be published.
40. Gumiński C., J. Phase Equil., 16, 333 (1995).
41. Gumiński C., ibid., 17,443 (1996).
42. Murray J.L., Phase Diagrams of Binary Titanium Alloys, American Society for Metals, Metals Park, 1987, p. 140.
43. Gumiński C., J. Phase Equil., 24,469 (2003).
44. Gumiński C., ibid., 16, 334 (1995).
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46. Gumiński C., J. Phase Equil., 14, 388 (1993).
47. Gumiński C., ibid., 22, 684 (2001).
48. Gumiński C., ibid., 13, 657 (1992).
49. Venkatraman M. and Neuman J.P., Bull. Alloy Phase Diagr., 10,157 (1989).
50. Gumiński C., J. Phase Equil., 15, 108 (1994).
51. Nagender Naidu S.V. and Rama Rao P., Phase Diagrams of Binary Tungsten Alloys, Indian Institute of Metals, Calcuta, 1991, p. 122.
52. Moser Z. and Gumiński C., J. Phase Equil., 14, 726 (1993).
53. Gumiński C„ ibid., 14, 220 (1993).
54. Gumiński C„ ibid., 23, 184 (2002).
55. Gumiński C., Phase Diagrams of Binary Iron Alloys, H. Okamoto, Ed., American Society for Materials, Materials Park, 1993, p. 174.
56. Gumiński C., J. Phase Equil., 16, 83 (1995).
57. Gumiński C„ ibid., 16, 81 (1995).
58. Gumiński C., ibid., 14, 643 (1993).
59. Gumiński C„ ibid., 24, 373 (2003).
60. Gumiński C., ibid., 23, 537 (2002).
61.Milare E., Fertonani F.L., Benedetti A.V. andlonashiro M., J. Thermal Anal. Calor., 59, 617 (2000).
62. Gumiński C., Lee S.Y. and Nash P., Phase Diagrams of Binary Nickel Alloys, American Society for Materials, Materials Park, 1991, p. 167.
63. Gumiński C„ Bull. Alloy Phase Diagr., 11, 22 (1990).
64. Barański A., Kryska A. and Galus Z., J. Electroanal. Chem., 349, 341 (1993).
65. Gumiński C., J. Less-Common Met., 168, 329 (1991).
66. Gumiński C., Bull. Alloy Phase Diagr., 11,26 (1990).
67. Chakrabarti D.J., Gumiński C. and Laughlin D.E., Phase Diagrams of Binary Copper Alloys, American Society for Materials, Materials Park, 1994, p. 205.
68. Baren M.R., J. Phase Equil., 17, 122 (1996).
69. Okamoto H. and Massalski T.B., Bull. Alloy Phase Diagr., 10, 50 (1989).
70. Zabdyr L.A. and Gumiński C., J. Phase Equil., 16, 353 (1995).
71. Gumiński C. and Zabdyr L.A., ibid., 13, 401 (1992).
72. Gumiński C., unpublished.
73. McAlister A.J., Bull. Alloy Phase Diagr., 6, 219 (1985).
74. Gumiński C. and Zabdyr L.A., J. Phase Equil., 14, 719 (1993).
75. Okamoto H., Phase Diagrams of Indium Alloys, American Society for Materials, Materials Park, 1991, p. 129.
76. Gumiński C., J. Phase Equil., 15, 111 (1994).
77. Gumiński C., ibid., 14, 219 (1993).
78. Gumiński C„ ibid., 22, 682 (2001).
79. Gumiński C„ ibid., 20, 344 (1999).
80. Zabdyr L.A. and Gumiński C„ ibid., 14, 743 (1993).
81. Zabdyr L.A. and Gumiński C., ibid., 14, 734 (1993).
82. Gumiński C„ ibid., 18, 101 (1997).
83. Gumiński C., to be published.
84. Gumiński C., J. Phase Equil., 17,419 (1996).
85. Gumiński C., Bull. Alloy Phase Diagr., 11, 317 (1990).
86. Zabdyr L.A. and GumiAski C., J. Phase Equil., 17, 230 (1996).
87. Gumiński C„ ibid., 20, 85 (1999).
88. Sharma R.C., Chang Y.A. and Gumiński C., ibid., 14, 100 (1993).
89. Sharma R.C., Chang Y.A. and Gumiński C., ibid., 13, 663 (1992).
90. Sharma R.C., Chang Y.A. and Gumiński C., ibid., 16, 338 (1995).
91. Gumiński C„ ibid., 16, 337 (1995).
92. Gumiński C., ibid., 22, 578 (2001).
93. Gumiński C„ ibid., 15, 101 (1994).
94. Gumiński C., ibid., 21, 539 (2000).
95. Gumiński C., ibid., 18, 206 (1997).
96. Gumiński C„ ibid., 16, 525 (1995).
97. Gumiński C., unpublished.
98. Gumiński C., J. Phase Equil., 17,442 (1996).
99. Gumiński C. and Galus Z .,Intermetallic Compounds in Mercury, IUPAC Solubility Data Series, Vol. 51, J.G. Osteryoung and M.M. Schreiner, Eds., Pergamon, Oxford, 1992.
100. Gumiński C., Z. Metallk., 77, 87 (1986).
101. Galus Z„ Pure Appl. Chem., 56, 635 (1984).
102. Gumiński C. and Galus Z., J. Electroanal. Chem., 83, 139 (1977).
103. Igolinskii V.A. and Shalaevskaya V.N., Elektrokhimiya, 10, 536 (1974).
104. Gumiński C., J. Mater. Sei., 24, 2661 (1989).
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110. Korshunov V.N.,KhlystovaK.B.,Kraev V. A. and Vacherikova S.G., Elektrokhimiya, 21,1233(1985).
111. Tamamushi R., J. Electroanal. Chem., 109, 353 (1980).
112. Chlistunoff J., Doctor thesis, University of Warsaw, Poland, 1988.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0024-0110