The Influence of Solvent on the Reaction Between Iron (II), (III) and tert-Butyl Hydroperoxide-Electrochemical Catalytic Processes of Reductants

• Autorzy: Pacześniak T. , Sobkowiak A.
• Języki publikacji: EN

Abstrakty

EN

It has been found that tert-butyl hydroperoxide is analogous to hydrogen peroxide with respect to their reactivity towards iron(II) and iron(III). In water iron(II) is oxidized by tert-butyl hydroperoxide, whereas in acetonitrile iron(III) is reduced by tert-butyl hydroperoxide. The last reaction when performed by cyclic-voltammetry is an example of electrochemical catalytic processes of reductants.

Słowa kluczowe

EN

Fenton's reagent; tert-butyl hydroperoxide activation; electrochemical catalytic current

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 9
• Strony: 1611--1618
• Opis fizyczny: Bibliogr. 24 poz., rys.

Twórcy

autor

Pacześniak T.

• Faculty of Chemistry, Rzeszów University of Technology, P. O. Box 85, 35-959 Rzeszów, Poland

autor

Sobkowiak A.

• Faculty of Chemistry, Rzeszów University of Technology, P. O. Box 85, 35-959 Rzeszów, Poland

Bibliografia

• 1. Galus Z., Fundamentals of Electrochemical Analysis, 2nd ed. Ellis Horwood, New York 1994.
• 2. Sawyer D.T., Sobkowiak A., Roberts J. R. Jr., Electrochemistry for Chemists, 2nd ed., Wiley, New York 1995.
• 3. Bard A.J. and Faulkner L.R., Electrochemical Methods. Fundamentals and Applications, 2nd ed. Wiley, New York 2001.
• 4. Sawyer D.T., Sobkowiak A. and Matsushita T., Acc. Chem. Res., 29, 409 (1996).
• 5. Barton D.H.R., Chem. Soc. Rev., 237 (1996).
• 6. Barton D.H.R., Tetrahedron, 54, 5805 (1998).
• 7. Barton D.H.R. and Sobkowiak A., New J. Chem. 20, 926 (1996).
• 8. Jones C.W., Applications of Hydrogen Peroxide and Derivatives, Royal Society of Chemistry, Cambridge 1999.
• 9. Alvarez-Gallegos A. and Pletcher D., Electrochim. Acta, 44, 853 (1998).
• 10. Alvarez-Gallegos A. and Pletcher D., Electrochim. Acta, 44, 2483 (1999).
• 11. Que L., Jr. and Ho RY.N., Chem. Rev., 96, 2607 (1996).
• 12. Wallar B.J. and Lipscomb J.D., Chem. Rev., 96, 2625 (1996).
• 13. Biomimetic Oxidations Catalyzed by Transition Metal Complexes, Meunier B., Ed., Imperial College Press, London 2000.
• 14. Zaitsev P.M., Zhdanov S.I. and Nikolaeva T.D., Russ. Chem. Rev., 51, 552(1982) {Usp. Khim., 51,968 (1982)}.
• 15. Sobkowiak A. and Fleszar B., Electrochim. Acta, 26, 847 (1981).
• 16. Walling C., Acc. Chem. Res., 31, 155 (1998).
• 17. MacFaul P.A., Wayner D.D.M. and Ingold K.U., Acc. Chem. Res., 31, 159 (1998).
• 18. Goldstein S. and Meyerstein D., Acc. Chem. Res., 32, 547 (1999).
• 19. Paczesniak T. and Sobkowiak A., J. Mol. Catal. A, 194, 1 (2003).
• 20. Minisci F., Fontana F., Araneo S., Recupero F. and Zaho L., Synlett, 119 (1996).
• 21. MacFaul P.A., Arends I.W.C.E., Ingold K.U. and Wayner D.D.M., J. Chem. Soc., Perkin Trans. 2, 135 (1997).
• 22. Barton D.H.R., Le Gloahec V.N., Patin H. and Launay F., New J. Chem., 559 (1998).
• 23. Barton D.H.R., Le Gloahec V.N. and Patin H., New J. Chem., 656 (1998).
• 24. Kolthoff I.M., Sandell E.B., Meehan E.J., Bruckenstein S., Quantitative Chemical Analysis, 4th ed., MacMillan, New York 1969, p. 854.