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Abstrakty
A series of polymer electrolytes, based on ionic liquid (EMIm)3PO4, and the polymers PAN, PVdF, PVdF-HFP, PVA and PEO were prepared as thin-foils, using the casting technique. The composite electrolytes showed conductivity at a level of ca. 10 mS/cm, apart from the system PEO-(EMIm)3PO4. The electrochemical stability window of the electrolytes based on PAN, PVdF and PVdF-HFP, as determined at the glassy carbon, was at a level of ca. 4V. The solid electrolytes polymer-(EMIm)3PO4 were applied in a series of double-layer capacitors. The specific capacity expressed versus the active carbon mass was at a very high level of 230 F/g (for an activated carbon powder with a specific surface area of ca. 2600 m2/g). Good specific conductivity, a broad electrochemical stability window and very high specific capacity suggest that the polymer-(EMIm)3PO4 composites are good candidates for application in double layer capacitors.
Słowa kluczowe
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Rocznik
Tom
Strony
1371--1378
Opis fizyczny
Bibliogr. 38 poz., rys.
Twórcy
autor
- Faculty of Chemical Technology, Poznan University of Technology, ul. Piotrowo 3, PL-60 965 Poznań, Poland
autor
- Faculty of Chemical Technology, Poznan University of Technology, ul. Piotrowo 3, PL-60 965 Poznań, Poland
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0024-0080