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On Benefits of the Zero-Pole Representation of Electrochemical Impedance Spectroscopy Data Clodse to Discontinuity Point

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Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Unusual electrochemical impedance spectroscopy (eis) data obtained for dissolution and passivation of a copper rotating disc electrode in copper sulphate solution and analogous to data reported recently by other authors was represented as a rational function of frequency in terms of zeros and poles. The conditions of stability under potential control (pc) and galvanostatic control (gc) were formulated based on values of zeros and poles and were illustrated with calculated responses to potential and current steps. The loss of stability under pc due to resistance added in series was interpreted as change of the sign of the impedance zero.
Rocznik
Strony
1245--1253
Opis fizyczny
Bibliogr. 68 poz., rys.
Twórcy
autor
  • Institute of Physical Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0024-0069
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