Synthesis of Block and Random Copolymers of Isoprene via Two-Electron Transfer Mechanism

Janeczek, H.; Jedliński, Z.

Artykuł - szczegóły

Tytuł artykułu

Synthesis of Block and Random Copolymers of Isoprene via Two-Electron Transfer Mechanism

Autorzy

Janeczek H. , Jedliński Z.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Supramolecular complexes of alkali metals, capable of two electron transfer and generation of carbanions have been utilized in the polymerization of isoprene. The "living" polyisoprene blocks were subsequently used to react with styrene to produce the relevant block copolymers. The polyisoprene-polystyrene random copolymers were also obtained. The novel type of anionic polymerization initiated via novel supramolecular catalyst yields polyisoprene copolymers with well defined structure and properties.

Słowa kluczowe

anionic polymerization copolymers of isoprene two-electron transfer polyisoprene-polystyrene copolymers

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2004

Tom

Vol. 78 / nr 8

Strony

1037--1046

Opis fizyczny

Bibliogr. 56 poz., rys.

Twórcy

autor

Janeczek H.

Polish Academy of Sciences, Centre of Polymer Chemistry, 34, M.Curie-Skłodowska St., 41-800 Zabrze, Poland

autor

Jedliński Z.

Polish Academy of Sciences, Centre of Polymer Chemistry, 34, M.Curie-Skłodowska St., 41-800 Zabrze, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0024-0053