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Abstrakty
Several mononuclear Ni(II) and Co(II) complexes of bidentate salicylaldimines (LxH), derived from 3,5-di-tert-butyl-2-hydroxybenzaldehyde with biologically active amines [1-(3-aminopropyl)imidazole, 4-(3-aminopropyl)morpholine, 1-(3-aminopropyl)-2-pyrrolidinone], have been synthesized. The complexes have been characterized by FT-IR, UV-vis, MS, 1H-NMR and 13C-NMR, magnetic susceptibility measurements, thermogravimetric analyses (TGA) and electrochemistry. As a result of thermal analyses, Co(L3)2 has highest thermal stability of the complexes, whereas the smallest one has Ni(L2)2. Electrochemical experiments indicated that Ni(II) and Co(II) complexes show quasi reversible reduction to Ni(I) and Co(I), respectively.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
903--909
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
autor
- Department of Chemistry, Harran University, 63100 Sanliurfa, Turkey
autor
- Department of Chemistry, Harran University, 63100 Sanliurfa, Turkey
autor
- Department of Chemistry, Harran University, 63100 Sanliurfa, Turkey
autor
- Department of Chemistry, Harran University, 63100 Sanliurfa, Turkey
Bibliografia
- 1. Herzfeld R. and Nagy P., Spectrosc. Lett., 31, 57 (1999).
- 2. Temel H., Ilhan S., Sekerci M. and Ziyadanogullari R., Spectrosc. Lett., 35, 219 (2002).
- 3. Sheldon R.A. and Kochi J.R., Metal Catalysed Oxidation of Organic Compounds. Academic Press New York, (1981)
- 4. (a) Kaim W., Coord. Chem. Rev., 76, 187 (1987); (b) Meyer T.J., Acc. Chem. Res., 11, 94 (1978); (c) Richardson D.E. and Taube H., Coord. Chem. Rev., 60,107(1984);(d)ReimersJ.R.andHushN.S,(eds), Electron Transfer in Biology and the Solid State, Am. Chem. Soc., Washington, DC, 1990.
- 5. (a) Whittaker M.M., In Bioinorganic Chemistry of Copper, Karlin KD. and Tyeklar Z., eds. Chapman & Hall, New York, London, 1993; (b) Halfen J.A., Toung V.G. and Tolman W.B., Angew. Chem. Int. Ed Engl., 35, 1687 (1996).
- 6. (a) Solomon E.I., Sundaram U.M. and Makonkin T.E., Chem. Rev., 96, 2563 (1996); (b) Huber R., Angew. Chem. Int. Ed. Engl, 28, 848 (1989); (c) Mansuy D„ PureAppl. Chem., 59, 759 (1997).
- 7. (a) Kahn O., Angew. Chem. Int. Ed. Engl., 24,834 (1985); (b) Klinman J.P., Chem. Rev., 96,2541 (1996); (c) Zurita D., Menage S., Pierre J. L. and Aman E.S., J. Biol. Inorg. Chem., 2, 46 (1997).
- 8. Larrow J.F., Jacobsen E.N., Gao Y., Hong Y., Nie X. and Zepp C.M., J. Org. Chem., 59, 1939 (1994).
- 9. Eamshaw A., Introduction to Magnetochemistry, Academic Press, London, p. 4, 1968.
- 10. Ayad M.I., Salam S.A. and Mabrouk H.E., Thermochim. Acta., 1, 65 (1991).
- 11. Koksal M., Turner M. and Serin S., Synth. React. Inorg. Met-Org. Chem., 26(9), 1577 (1996).
- 12. Turner M., Koksal M. and Serin S., Synth. React. Inorg. Met-Org Chem., 27(9), 775 (1997).
- 13. Garg B.S., Singh P.K. and Sharma J.L., Synth. React. Inorg. Met-Org. Chem., 30, 803 (2000).
- 14. Tas E., Kasumov V.T., Sahin O. and Özdemir M., Trans. Met. Chem., 27, 442 (2002).
- 15. (a) Gerald O. and Dudek E.P., J. Am. Chem. Soc., 88, 2407 (1966); (b) Alexander P.W. and Sleet R.J., Aust. J. Chem., 23, 1183 (1970); (c) Seliskar C.J., J. Phys. Chem., 81, 1331 (1977).
- 16. Nishida Y. and Kida S., Coord. Chem. Rev., 27, 275 (1979).
- 17. (a) Kasumov V.T., Trans. Met. Chem., 27, 228 (2002); (b) Sheat S.V. and Waters T.N., J. Inorg Nucl Chem., 26, 1221 (1964).
- 18. Guangbin W., Spectrosc. Lett., 32(4), 1061 (1999).
- 19. (a) Everett G.W. and Holm R.H.,./. Am. Chem. Soc., 87,2117(1965); (b) Sacconi L., Ciampolini M. and Nardi N.,J.Am. Chem. Soc., 86,819 (1964); (c) Holm R.H. and O’Connor M.J., Prog. Inorg. Chem 14 214(1971).
- 20. Satpathy K.C., Mishra H.P. and Mishra R., J. Inorg. Nucl. Chem., 43(11), 2765 (1981).
- 21. (a) West B., J. Chem. Soc., 3123 (1952); (b) Maurya R.C., Patel P. and Rajput S., Synth. React. Inorg Met-Org. Chem., 33(5), 817 (2003).
- 22. Bard A.J. and Faulkner L.R., (Eds), Electrochemical Methods: Fundamentals and Applications 2nd edn., Wiley, NY, 2001.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0024-0039