Selective Formation of Isopropyl alfa- and beta-Glucofuranosides in One Pot Reaction from D-Glucose and Propanol-2 Promoted by V2O5

• Autorzy: Tyrlik S. , Bednarek E. , Bocian W. , Sitkowski J. , Maurin J. , Olejnik M. , Nalewajko B. , Kozerski L.
• Języki publikacji: EN

Abstrakty

EN

Reaction of D-glucose with propanol-2 promoted by V2O5 gives rise exclusively to isopropylglucofuranosides. Their tetraacetates were prepared; X-ray structure of one of tetraacetates was determined. 1H and 13C NMR signals assignment was done by COSY and GMBC techniques. Mechanism of selective glucosidation was discussed.

Słowa kluczowe

EN

D-glucose; glucofuranosides; vanadium pentoxide; NMR; X-ray structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 6
• Strony: 803--814
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Tyrlik S.

• Department of Chemistry, University of Podlasie, 08-110 Siedlce, ul. 3-go Maja 54, Poland

autor

Bednarek E.

• National Institute of Public Health, 00-725 Warszawa, ul. Chełmska 30/34, Poland
• Industrial Chemistry Research Institute, 01-793 Warszawa, ul. Rydygiera 8, Poland

autor

Bocian W.

• National Institute of Public Health, 00-725 Warszawa, ul. Chełmska 30/34, Poland

autor

Sitkowski J.

• National Institute of Public Health, 00-725 Warszawa, ul. Chełmska 30/34, Poland
• Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warszawa, ul. Kasprzaka 44, Poland

autor

Maurin J.

• National Institute of Public Health, 00-725 Warszawa, ul. Chełmska 30/34, Poland
• Institute of Atomic Energy, 05-400 Otwock-Świerk, Poland

autor

Olejnik M.

• Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warszawa, ul. Kasprzaka 44, Poland

autor

Nalewajko B.

• Department of Chemistry, University of Podlasie, 08-110 Siedlce, ul. 3-go Maja 54, Poland

autor

Kozerski L.

• National Institute of Public Health, 00-725 Warszawa, ul. Chełmska 30/34, Poland
• Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warszawa, ul. Kasprzaka 44, Poland

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