Synthesis, Structure and Non-Linear Optical Properties of a Copper(II) Ethyl Bisulfate Two-Dimensional Supramolecular Compound {Cu(Him)4(Cu(Him)4(CH3CH2OSO3H)2]

• Autorzy: Li Y. , Lu J. , Cui X. , Xu J. , Sun Y. , Pan L. , Bie H. , Zhang X.
• Języki publikacji: EN

Abstrakty

EN

A novel copper(II) ethyl bisulfate complex [Cu(Him)4(Eb)2] 1 (Him = imidazole, Eb = ethyl bisulfate) has been prepared and characterized by means of elemental analysis, IR and ESR. The structure was determined by single crystal X-ray diffraction analysis, which suggests that compound 1 exhibits a two-dimensional supramolecular structure through hydrogen bonds. Compound 1 displays strong third-order non-linear optical (NLO) absorption and refraction with absorption coefficient _2 1.10_10-11 m_w-1 and refractive index n2 5.60_10-16m2_w-1. The third-order non-linear optical susceptibility _(3) of compound 1 is 3.07_10-10 esu.

Słowa kluczowe

EN

copper(II) ethyl bisulfate compound; supramolecular structure; hydrogen bond; third-order non-linear optical property

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 6
• Strony: 779--787
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Li Y.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Lu J.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Cui X.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China
• Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou 350002, P. R. China

autor

Xu J.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Sun Y.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Pan L.

• College of Physics, Jilin University, Changchun 130023, P. R. China

autor

Bie H.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Zhang X.

• College of Chemistry and State Key Laboratory Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China

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