The Reactions of 2-(Bromoseleno) benzenesulfonyl Chloride with Primary Amines toward 2,2'-Diselenobis(benzenesulfonamides) and 1,2,3-Benzothiaselenazole 1,1-Diodides: New oxygen-Transfer Agents, Antimicrobials and Virucides

• Autorzy: Potaczek P. , Giurg M. , Kloc K. , Maliszewska I. , Piasecki E. , Piętka M. , Młochowski J.
• Języki publikacji: EN

Abstrakty

EN

The reaction of title compound 6 with primary aliphatic or aromatic amines was investigated. The products were 2,2_-diselenobis(benzenesulfonamides) (4) accompanied in some cases by 1,3,2-benzothiaselenazole 1,1-dioxides (3). Exceptionally, when aniline was a reagent, 2-(sulfamoylphenyl)phenylselenenylanilide was produced. These results are interpreted in the light of the proposed mechanisms. The compounds 3 and 4 exhibited catalytic activity in hydroperoxide oxidation of cyclohexanone (12) and 1-naphthaldehyde N,N-dimethylhydrazone (17). Although they were inactive against patogenic bacteria and fungi an appreciable antiviral activity against HSV-1 and EMCV of the compounds 3b, 3c and 4b was observed.

Słowa kluczowe

EN

amines; antimicrobials; oxidation; selenium compounds; virucides

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 5
• Strony: 687--697
• Opis fizyczny: Bibliogr. 20 poz., rys.

Twórcy

autor

Potaczek P.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Giurg M.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Kloc K.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Maliszewska I.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Piasecki E.

• Laboratory of Virology, Institute of Immunology and Experimental Therapy, Polish Academy of Sciences, R. Weigla 12, 53-144 Wrocław, Poland

autor

Piętka M.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Młochowski J.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-375 Wrocław, Poland

Bibliografia

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