Spectrochemical Properties of Noncubic Transition Metal complexes in Solutions. XVI. Angular Overlap Treatments of cis-Bis(2,2'-bipyridyl)oxalatechromium(III) Iodide in Aqueous Solution

Kurzak, K.; Biernacki, K.

Artykuł - szczegóły

Tytuł artykułu

Spectrochemical Properties of Noncubic Transition Metal complexes in Solutions. XVI. Angular Overlap Treatments of cis-Bis(2,2'-bipyridyl)oxalatechromium(III) Iodide in Aqueous Solution

Autorzy

Kurzak K. , Biernacki K.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The electronic absorption spectrum of cis-[Cr(ox)(bpy)2]I (bpy = 2,2_-bipyridyl; ox = oxalate ion) of aqueous (H2O) solution, has been measured at room temperature and interpreted using the angular overlap model (AOM), and assuming C2v as the effective symmetry. All the experimental transitions are derived from Gaussian analysis of the solution spectrum. The calculations of the ligand field parameters take into account all the transitions, which are required from the ligand field theory (except those energetically higher than the range of the measured spectrum). The coordination

Słowa kluczowe

angular overlap model electronic spectra chromium(III) complexes 2,2'-bipyridyl oxalate molecular structure low symetry aqueous solution

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2004

Tom

Vol. 78 / nr 5

Strony

673--679

Opis fizyczny

Bibliogr. 27 poz. rys.

Twórcy

autor

Kurzak K.

Department of Chemistry, University of Podlasie, 08-110 Siedlce, Poland

autor

Biernacki K.

Department of Chemistry, University of Podlasie, 08-110 Siedlce, Poland

Bibliografia

1. Kuźniarska-Biemacka I., Kurzak K., Kurzak B. and Jezierska J., J. Solution Chem., 32, 719 (2003).
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21. Cambridge Structural Database, Version 5.25, Cambridge Crystallographic Data Center, Cambridge: England, November 2003.
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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0024-0014