Nickel(II) Dithiocarbamates with Bis(2-diphenylphosphinoethyl)phenylphosphine

• Autorzy: Pastorek R. , Kamenicek J. , Husarek J. , Cvek B. , Malon M. , Pavlicek M. , Sindelar Z.
• Języki publikacji: EN

Abstrakty

EN

A Ni(II) dithiocarbamates with the tridentate P,P,P-ligand of composition [Ni(pe2dtc)(triphosI)]X (triphosI = C34H33P3 = bis(2-diphenylphosphinoethyl) phenylphosphine, pe2dtc = dipentyldithiocarbamate, X = Cl, PF6, ClO4), [Ni(bz2dtc)(triphosI)]X (bz2dtc = dibenzyldithiocarbamate, X = Cl, PF6) and [Ni(cetdtc)(triphosI)]X (cetdtc = cyclohexylethyldithiocarbamate, X = Cl, PF6, BPh4, ClO4) have been synthesized and studied by thermal analysis, IR and UV/VIS spectroscopy, 31P{1H}-NMR spectroscopy, magnetochemical and conductivity measurements. All complexes are diamagnetic, 1:1 electrolytes. X-ray structural analysis was solved for the [Ni(pe2dtc)(triphosI)]PF6 and [Ni(bz2dtc)(triphosI)]PF6; the presence of NiS2P3

Słowa kluczowe

EN

Ni(II)dithiocarbamate; synthesis; physico-chemical study; X-ray structural analysis; 31P{1H}-NMR spectroscopy

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 5
• Strony: 623--633
• Opis fizyczny: Bibliogr. 37 poz., rys.

Twórcy

autor

Pastorek R.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Kamenicek J.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Husarek J.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Cvek B.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Malon M.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Pavlicek M.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Sindelar Z.

• Department of Inorganic Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

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