Stereoselection at the Steady State within radicals - How far can we go ?

• Autorzy: Staliński K.
• Języki publikacji: EN

Abstrakty

EN

Stereoselection at the steady state is a process, which results from a complex interplay of reaction pathways that diverge and reconverge at various points. Therefore, it can be considered as a manipulation of stereocontrol mainly by reaction topography. The advantages of this process are at least twofold: First, stereoconvergence allows the system to exceed the yield of the initial stereoconvergent event, where stereomeric transition states compete. Second, a successive resolution of the reactive intermediates by chemoselective events allows the system to generate high stereomeric excess, practically without any stereoselective competition. While illustrated with radicals, the process may prove useful in other fields of chemistry.

Słowa kluczowe

EN

stereoselection; steady state; radicals

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 5
• Strony: 611--622
• Opis fizyczny: Bibliogr. 36 poz., rys.

Twórcy

autor

Staliński K.

• Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland,

Bibliografia

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