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Semi-Conductive Materials Based on the Titanium Dioxide Doped with Zinc: Catalytic Activity for Copper Deposition and Effect of UV-Irradiation

Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Novel semiconductive materials containing TiO2 dispersion, doped with zinc and additional modifying salts of Cu2+, Fe2+, and Co2+, have been obtained. Such materials can be used as effective catalysts in the Cu2+ reduction. Exposition to UV-light followed by the dark storage leads to complex changes of the catalytic activity of TiO2products. Detailed character of the changes depends on the presence of a doping agent and on the nature of modifying salts' anion. The scheme of the electron transfer processes has been proposed to describe changes of the activity.
Rocznik
Strony
553--560
Opis fizyczny
Bibliogr. 25 poz., rys.
Twórcy
autor
  • Chernivtsi National University, Kotsiubinsky St. 2, Chernivtsi, 58012, Ukraine, igorw@lenta.ru
Bibliografia
  • 1. Vishenkov S.A., Chemical and Electrochemical Methods of Metal Covering Deposition, Moscow, Nauka, 1975 (In Russian).
  • 2. Salkauskas M.l. and VyaSilis A.Yu., Chemical Metallization of Plastics, Leningrad, Nauka, 1977 (In Russian).
  • 3. Mazurkevich Ya.S., Zozulia N.I., Rotaru V.K., Yurov L.L., Pozhidaeva Z.M., Kobasa I.M. and Blashku A.I., USSR Pat. 1688778; USSR Innov., 58 (1991) (In Russian).
  • 4. Mazurkevich Ya.S., Zozulia N.I. and Kobasa I.M., Khim. i Khim. Tech., 41, 98 (1998) (In Russian
  • 5. Mazurkevich Ya.S. and Kobasa I.M., Inorg. Mater., 33, 1403 (1997) (In Russian).
  • 6. Sviridov V.V., Silver-free Photographic Materials, Leningrad, Khimiya, 1984 (In Russian).
  • 7. Pomogailo A.D., Rosenberg A.S. and Uflyand I.E., Metal Nano-particles in Polymers, Moscow Nauka. 2000 (In Russian).
  • 8. Roldugin V.I., Usp. Khim., 69, 899 (2000) (In Russian).
  • 9. Buhtiyarov V.l. and Slinko M.G., Usp. Khim., 70, 167 (2001) (In Russian).
  • 10. Sergeev G.B., Usp. Khim., 70, 915 (2001) (In Russian).
  • 11. Myamlin V.A. and Pleskov Yu.V., Electrochemistry of Nanoconductors, Moscow, Nauka, 1965 (In Rus¬sian).
  • 12. Gurevich Yu. Ya. and Pleskov Yu.V., Photoelectrochemistry of Semiconductors, Moscow, Nauka, 1983 (In Russian).
  • 13. Arutyunyan V.M., Photoelectric Transformation of the Solar Energy, Ed. Zamaraev K.I, Novosibirsk, Nauka, 1, 74,1985 (In Russian).
  • 14. Energy Resources through Photochemistry and Catalysis. Ed. M. Grätzel, NY, Academic Press, 1983.
  • 15. Fox M.A. and Dulay M.T., Chem. Rev., 93, 341 (1993).
  • 16. Kamat P.V., Chem. Rev., 93, 267 (1993).
  • 17. Kryukov A.I., Kuchmy S.Ya. and Pokhodenko V.D., Theor. Exper. Chem., 30, 141 (1993).
  • 18. Linsebjgler A.L., Lu G. and Jates T.J., Chem. Rev., 95, 735 (1995).
  • 19. Hoffmann M.R., Martin S.T., Choi W. and Bahnemann D.W., Chem. Rev., 95, 69 (1995).
  • 20. Kryukov A.I., Kuchmy S.Ya. and Pokhodenko V.D., Theor. Exper. Chem., 33, 306 (1997).
  • 21. Kryukov A.I., Kuchmy S.Ya. and Pokhodenko V.D., Theor. Exper. Chem., 36, 69 (2000).
  • 22. Kulak A.I., Electrochemistry of the Semiconductive Heterostructures, Minsk, Univ. Press, 1986 (In Rus¬sian).
  • 23. Mazurkevich Ya.S. and Kobasa I.M., Khim. i Khim. Tech., 41, 59 (1998) (In Russian).
  • 24. Kobasa I.M., Mazurkevich Ya.S. and Zozulia N. I., Theor. Exper. Chem., 39, 305 (2003).
  • 25. Henglein A., Phys. Chem., 97, 5447 (1993).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0023-0200
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