Hydrogen Peroxide Oxidation of Naphthalene Derivatives Catalyzed by Poly(bis-1,2-diphenylene) Diselenide

• Autorzy: Giurg M. , Syper L. , Młochowski J.
• Języki publikacji: EN

Abstrakty

EN

Oxidation of 1- and 2-substituted naphthalenes (1) with 30% hydrogen peroxide in the presence of poly(bis-1,2-diphenylene) diselenide (PPDS) has been investigated. Depending on the substrate used trans-2-carboxycinnamic acid (2), and its isomer, (1-oxo-1,3-dihydroisobenzofuran-1-yl)acetic acid (3) or 2-naphthoic acid (4b) was a major product. Oxidation of hydroxynaphthalenes 1b and 1c is a convenient way to obtain trans-2-carboxy cinnamic acid (2) in almost quantitative yield. The mechanism of the reaction is postulated.

Słowa kluczowe

EN

cinnamic acids; diselenides; hydrogen peroxide; hydroxynaphthalenes; oxidation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 2
• Strony: 231--248
• Opis fizyczny: Bibliogr. 25 poz., rys.

Twórcy

autor

Giurg M.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

autor

Syper L.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

autor

Młochowski J.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

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