Synthesis, Characterization and Crystal Structure of (Z)-1-[2-(Tri-o-tolylstannyl)vinyl]-1-cyclopentanol and Its o-Tolylhalostannyl Derivatives

• Autorzy: Zhu D. , Lu S. , Mei Z. , Gao W. , Zhang Y. , Mu Y. , Wang Z.
• Języki publikacji: EN

Abstrakty

EN

(Z)-1-[2-(Tri-o-tolylstannyl)vinyl]-1-cyclopentanol (1) was synthesized by the additive reaction of 1-ethynylcyclopentanol with tri-o-tolyltin hydride. One or two of the o-tolyl groups of compound 1 was substituted by I, Br or Cl to yield derivatives of the type CH2(CH2)3CH(OH)CH=CHSn(o-tol)3-nXn [n = 1, X = I (2), Br (3), Cl (4); n = 2, X = Br (5)]. The compounds 1-5 were characterized by elemental analysis, 1H NMR and FT-IR spectroscopy. The crystal and molecular structures of 1 and 2 have been determined by single crystal X-ray diffraction analysis. The Sn atom in 1exhibits a tetrahedral geometry distorted towards trigonal bipyramid, due to a weak intramolecular interaction between Sn and hydroxyl O atoms [2.813(4) A], while the Sn atom in 2 adopts a trigonal bipyramidal geometry with a significant Sn(1) O(1) interaction [2.553(4) A].

Słowa kluczowe

EN

organotin compounds; aryltin compounds; FTIR spectroscopy; NMR spectroscopy; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2004
• Tom: Vol. 78 / nr 1
• Strony: 63--70
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Zhu D.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China
• School of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

autor

Lu S.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Mei Z.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Gao W.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Zhang Y.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Mu Y.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China
• Key Laboratory for Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130023, P. R. China

autor

Wang Z.

• School of Chemistry, Jilin University, Changchun 130023, P. R. China

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