The Syntheses, Crystal, Molecular and Electronic Structures of [ReBr3(py)3]0.42[ReBr2(NO)(py)3]0.58, trans-[ReBr4(OPPh3)2] and Orthorhombic Polymorph of mer-cis-[ReBr3(NO)(OPPh3)2]

• Autorzy: Machura B. , Dzięgielewski J. , Kusz J.
• Języki publikacji: EN

Abstrakty

EN

[ReBr3(py)3]0.42[ReBr2(NO)(py)3]0.58 (1), trans-[ReBr4(OPPh3)2] (2), [ReBr(NO)(dppe)2]Br (3) and orthorhombic polymorph of mer-cis- [Re(NO)Br3(OPPh3)2] (4) complexes have been synthesized by reactions of monoclinic polymorph of mer-cis-[Re(NO)Br3(OPPh3)2] with pyridine, bis(diphenylophosphino) ethane, 2,2_-bipyridine, 1,10-phenanthroline. The NO group in 1 and 4 is coordinated in a linear way. Due to nitrosyl/bromine compositional disorder, the shortening of Re-NO distance [1.68(5) A] and the elongation of N-O bond length [1.38(10) A] are observed in1. The N-O bond length in 4 is extremely short [0.94(1) A], which results probably from steric interactions of two mutually cis OPPh3 molecules and a large discrepancy of Re-O-P angle values.

Słowa kluczowe

EN

rhenium; nitrosyl; X-ray structure; electronic structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 5
• Strony: 519--533
• Opis fizyczny: Bibliogr. 43 poz., rys.

Twórcy

autor

Machura B.

• Department of Inorganic and Radiation Chemistry, Institute of Chemistry,University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland

autor

Dzięgielewski J.

• Department of Inorganic and Radiation Chemistry, Institute of Chemistry,University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland

autor

Kusz J.

• Institute of Physics, University of Silesia, 4th Uniwersytecka St., 40-006 Katowice, Poland

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