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Abstrakty
9,10-Bis(hydroxyimino)-4,8,11,15-tetra-aza-1,2,17,18-O-di-iso-propylideneoctadecane (H2L) was synthesized by the reaction of 1,2-O-iso-propylidene-4-aza-7-aminoheptane and anti-dichloroglyoxime in ethanol, containing an excess of NaHCO3 as a buffer to neutralize the HCl formed. The mononuclear metal complexes of this ligand have been synthesized with Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) salts. H2L forms mononuclear complexes [(HL)2M] with a metal ligand ratio of 1:2 with M = Co(II)_2H2O, Ni(II) and Cu(II). Zn(II) and Cd(II) form with H2L complexes [(H2L)(Cl)2M], which have a metalligand ratio of 1:1 and a dinuclear complex with UO2(VI). H2L forms the dinuclear complex [(HL)2(OH)2M2] with a metal ligand ratio of 1:1 withM=UO2(VI). Structures of the ligand and its metal complexes were identified by elemental analyses, IR, 1H and 13C NMR spectra and thermogravimetric analyses (TGA).
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
403--410
Opis fizyczny
Bibliogr. 38 poz., rys.
Twórcy
autor
- Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey
autor
- Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey
autor
- Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0023-0101