A New Substituted Bis(vic-dioxime) of Its Mono and Dinuclear Complexes

• Autorzy: Güngör O. , Canpolat E. , Kaya M.
• Języki publikacji: EN

Abstrakty

EN

9,10-Bis(hydroxyimino)-4,8,11,15-tetra-aza-1,2,17,18-O-di-iso-propylideneoctadecane (H2L) was synthesized by the reaction of 1,2-O-iso-propylidene-4-aza-7-aminoheptane and anti-dichloroglyoxime in ethanol, containing an excess of NaHCO3 as a buffer to neutralize the HCl formed. The mononuclear metal complexes of this ligand have been synthesized with Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) salts. H2L forms mononuclear complexes [(HL)2M] with a metal ligand ratio of 1:2 with M = Co(II)_2H2O, Ni(II) and Cu(II). Zn(II) and Cd(II) form with H2L complexes [(H2L)(Cl)2M], which have a metalligand ratio of 1:1 and a dinuclear complex with UO2(VI). H2L forms the dinuclear complex [(HL)2(OH)2M2] with a metal ligand ratio of 1:1 withM=UO2(VI). Structures of the ligand and its metal complexes were identified by elemental analyses, IR, 1H and 13C NMR spectra and thermogravimetric analyses (TGA).

Słowa kluczowe

EN

vic-dioxime; cobalt(II); nickel(II); copper(II); zinc(II); cadmium(II); uranyl(VI) complexes

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 4
• Strony: 403--410
• Opis fizyczny: Bibliogr. 38 poz., rys.

Twórcy

autor

Güngör O.

• Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey

autor

Canpolat E.

• Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey

autor

Kaya M.

• Department of Chemistry, Faculty of Arts and Sciences, University of Firat, 23119 Elazig, Turkey

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