1:3 Complex between beta-Cyclodextrin and Dendrimer with Three Branches Involving Four Glycine and One Adamantyl Group

• Autorzy: Dodziuk H. , Demchuk O. , Koźmiński W. , Dolgonos G.
• Języki publikacji: EN

Abstrakty

EN

The first-generation dendrimer, benzene-sym-tris-N,N,N-carbonyltriglycylglycine N_-1-adamantylamide, was synthesized by a modification of a described procedure. Its complexation with alfa-, beta- and gamma-cyclodextrins was studied by NMR. The complexation induced fit and NOESY studies indicate that, in agreement with molecular mechanics calculations, the complex with alfa-cyclodextrin is considerably stronger than those with beta- and gamma-cyclodextrins.

Słowa kluczowe

EN

dendrimers; synthesis; cyclodextrin complexes; NMR

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 3
• Strony: 333--340
• Opis fizyczny: Bibliogr. 12 poz., rys.

Twórcy

autor

Dodziuk H.

• Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Kasprzaka 44, Poland

autor

Demchuk O.

• Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Kasprzaka 44, Poland

autor

Koźmiński W.

• Department of Chemistry, Warsaw University, 02-093 Warsaw, Pasteura 1, Poland

autor

Dolgonos G.

• Institute of Physical Chemistry, Polish Academy of Sciences, 01-224 Warsaw, Kasprzaka 44, Poland

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