Free Energy Contribution Due to the Specific Solvation of Anions. A Comparison of "Pure" Acidity Solvent Scales

• Autorzy: Jaworski J. , Krygowski T.
• Języki publikacji: EN

Abstrakty

EN

Four "pure" acidity solvent parameters (i.e. assumed to be free from non-specific solvation) proposed in the literature on quite different basis: E of Koppel and Palm [1], EN of Krygowski et al. [2], _ of Taft and Kamlet [3,4] and SAof Catalán and Díaz [5] gave the same contribution of the specific solvation of chloride ion to its standard molar free energy of transfer between a given solvent and water, as expected for "pure" scales.

Słowa kluczowe

EN

solvent parameters; specific solvation; Lewis acidity

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 2
• Strony: 221--225
• Opis fizyczny: Bibliogr. 20 poz., rys.

Twórcy

autor

Jaworski J.

• Faculty of Chemistry, Warsaw University, Pasteura 1, 02-093 Warsaw, Poland

autor

Krygowski T.

• Faculty of Chemistry, Warsaw University, Pasteura 1, 02-093 Warsaw, Poland

Bibliografia

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