Synthesis of N-Unsubstituted 1,3-Thiazollidines by [2+3]-Cycloaddition of an Azomethine Ylide with Thiocarbonyl Compounds

• Autorzy: Gebert A. , Linden A. , Mlostoń G. , Heimgartner H.
• Języki publikacji: EN

Abstrakty

EN

1,3-Dipolar cycloadditions of azomethine ylides with thiocarbonyl compounds have been used for the preparation of N-unsubstituted 1,3-thiazolidines. The reactive 1- phenyl-N-(trimethylsilyl)azomethine ylide (1c) was generated in situ by treatment of N-(benzylidene)[(trimethylsilyl)methyl]amine (6) with trimethylsilyl triflate and CsF in HMPA. All cycloadditions proceeded non-regioselectively, which led to mixtures of 4-phenyl- and 2-phenyl-substituted 1,3-thiazolidines.

Słowa kluczowe

EN

azomethine ylides; 1,3-dipolar cycloadditions; thiocarbonyl ylides; 1,3 thiazolidines; crystal structure

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 2
• Strony: 157--167
• Opis fizyczny: Bibliogr. 41 poz., rys.

Twórcy

autor

Gebert A.

• Organisch-chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

autor

Linden A.

• Organisch-chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

autor

Mlostoń G.

• Section of Heteroorganic Compounds, University of Łódź, Narutowicza 68, PL-90-136 Łódź, Poland

autor

Heimgartner H.

• Organisch-chemisches Institut der Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich, Switzerland

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