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Abstrakty
Mixed ligand cobalt(II) complex with monodentate (water) and bidentate (Schiff base: salicylidene-2-aminothiazole) ligands has been characterized by elemental analyses, molar conductivities, ultraviolet (UV) and visible (VIS) spectroscopy. The electronic spectra of solids as well as solutions exhibit pseudo-octahedral coordination geometry for the cobalt centre. The molar conductivities indicate their non-electrolytic properties in solvents studied. Combined multi-technique experiments have been used to postulate theC2h geometry for the species in solutions and to determine the coordination properties of ligators and their bonding abilities (ligand-field parameters).
Wydawca
Czasopismo
Rocznik
Tom
Strony
13--19
Opis fizyczny
Bibliogr. 35 poz., rys.
Twórcy
autor
- Department of Chemistry, University of Podlasie, PL 08-110 Siedlce, Poland
autor
- Department of Chemistry, University of Podlasie, PL 08-110 Siedlce, Poland
Bibliografia
- 1. Kurzak K., Kuźniarska-Biemacka I. and Żurowska B., J. Solut. Chem., 28, 133 (1999).
- 2. Kuźniarska-Biemacka I., Bartecki A. and Kurzak K., submitted to publication
- 3. Kuźniarska-Biemacka I., Ph.D. Thesis, University of Technology, Wrocław 2001.
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- 7. Kurzak K. and Kuźniarska-Biemacka I., J. Solut. Chem., 27, 533 (1998).
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- 24. Kuźniarska-Biemacka I. and Kurzak K., J. Solut. Chem., in press.
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- 29. Samus. I.D., Taran, G.G., Mazus, M.D., Fung, F.N., Tsapkov, V.I., Popov, M.S. and Samus, N.M., Koord. Khim., 20, 123 (1994).
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Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BUJ1-0023-0059