Spectrochemical Properties of Noncubic Transition Metal Complexes in Solutions. XIII. Angular Overlap Treatment of Diaquabis(salicylideneaminothiazole)cobalt(II)

Kuźniarska-Biernacka, I.; Kurzak, K.

Artykuł - szczegóły

Tytuł artykułu

Spectrochemical Properties of Noncubic Transition Metal Complexes in Solutions. XIII. Angular Overlap Treatment of Diaquabis(salicylideneaminothiazole)cobalt(II)

Autorzy

Kuźniarska-Biernacka I. , Kurzak K.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Mixed ligand cobalt(II) complex with monodentate (water) and bidentate (Schiff base: salicylidene-2-aminothiazole) ligands has been characterized by elemental analyses, molar conductivities, ultraviolet (UV) and visible (VIS) spectroscopy. The electronic spectra of solids as well as solutions exhibit pseudo-octahedral coordination geometry for the cobalt centre. The molar conductivities indicate their non-electrolytic properties in solvents studied. Combined multi-technique experiments have been used to postulate theC2h geometry for the species in solutions and to determine the coordination properties of ligators and their bonding abilities (ligand-field parameters).

Słowa kluczowe

cobalt(II) complexes Schiff bases salicylidene-2-aminothiazole solutions electronic spectra angular overlap model

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2003

Tom

Vol. 77 / nr 1

Strony

13--19

Opis fizyczny

Bibliogr. 35 poz., rys.

Twórcy

autor

Kuźniarska-Biernacka I.

Department of Chemistry, University of Podlasie, PL 08-110 Siedlce, Poland

autor

Kurzak K.

Department of Chemistry, University of Podlasie, PL 08-110 Siedlce, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0023-0059