Interpretation of Vibrational Spectra of Liquid Water

• Autorzy: Chumaevskii N. , Rodnikova M. N.
• Języki publikacji: EN

Abstrakty

EN

Based on Raman spectral studies of H2O, D2O, HOD and aqueous solutions of various salts we suggest a new interpretation of vibrational spectra of liquid water. The striking result is obtained that a quite definite set of weak H-bonds corresponds to a quite definite set of the rotational reorientations of the water molecules. The contribution of each orientation depends on the temperature and on the nature of the solved salts.

Słowa kluczowe

EN

liquid water; Raman spectra; rotational reorientation; molecule mobility

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 9
• Strony: 1363--1370
• Opis fizyczny: Bibliogr. 12 poz., rys.

Twórcy

autor

Chumaevskii N.

• Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 31 Leninsky prospect, 119991 Moscow GSP-1, Russia

autor

Rodnikova M. N.

• Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 31 Leninsky prospect, 119991 Moscow GSP-1, Russia

Bibliografia

• 1. Scherer J.R., in: Clark R.J.H. and Hester R.E. (eds.), Advances in Infrared and Raman Spectroscopy, Hayden, London, 1978, vol. 5, p. 149,
• 2. Ratctiffe C.I. and Irish D.E., J Phys. Chem., 86, 4897 (1982).
• 3. Sokołowska A., J. Raman Spectr., 20, 779 (1989).
• 4. Zhelyaskov V., Georgiev G. and Nickolov Zh., J. Raman Spectr., 20, 67 (1989).
• 5. Arrigo G.D., Maisano G., Mallamace F., Migliardo P. and Wanderlingh F., J. Chem. Phys., 75, 4264 (1981).
• 6. Walrafen G.E., Hokmabadi M.S. and Yang W.-H., J. Chem. Phys., 85,6964 (1986).
• 7. Carey D.M. and Korenowski G.M., J. Chem. Phys., 108, 2669 (1998).
• 8. Chumaevskii N.A. and Rodnikova M.N., Dokl. Akad. Nauk, 364, 640 (1999).
• 9. Chumaevskii N.A,, Rodnikova M.N. and Sirotkin D.A., J. Mol. Liquids, 82,39 (1999).
• 10. Chumaevskii N.A., Rodnikova M.N. and Sirotkin D.A., J. Mol. Liquids, 91, 8! (2001).
• 11. Walrafen G.E., J. Chem. Phys., 48, 244 (1968)
• 12. Brooker M.H., The Chemical Physics of Solvation, Part B, Spectroscopy of Solvation, Elsevier, Amsterdam - Oxford -New York - Tokyo, 1986, p. 119. 4. Gaussian 98 (Revision A.9), M.J. Frisch, G.W. Trucks, H.B, Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, V.G, Zakrzewski, J.A. Montgomery, RE, Stratmann, J.C. Burant, S. Dapprich, J.M. Millam, A.D. Daniels, K.N. Kudin, M.C. Strain, O. Farkas, J. Tomasi, V. Barone, M. Cossi, R. Cammi, B., Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G.A. Petersson, P.Y. Ayala, Q. Cui, K. Morokuma, D.K. Malick, A.D. Rabuck, K. Raghavachari, J.B. Foresman, J. Cioslowski, J.V. Ortiz, B.B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, RL. Martin, D.J. Fox, T. Keith, M.A. Al-Laham, C.Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P.M. W. Gill, B.G. John¬son, W. Chen, M. W. Wong, J.L. Andres, M. Head-Gordon, E.S. Replogle and J.A. Pople, Gaussian, Inc. Pittsburgh PA, 1998.