Interactions, Stabilizing the Structure of Intermolecular Polycomplex Between Poly(vinyl alcohol) and Poly(acrylamide)

• Autorzy: Permyakova N. , Zheltonozhskaya T. , Demchenko O. , Momot L. , Filipchenko S. , Zagdanskava N. , Syromyatnikov V.
• Języki publikacji: EN

Abstrakty

EN

The structure and properties of the intermolecular polycomplex, formed by cooperative intermolecular hydrogen bonds between poly(vinyl alcohol) and poly(acrylamide), were investigated. By viscometry, gel chromatography and differential scanning calorimetry the characteristic composition of polycomplex was established. The compatibility of polymers and structural peculiarities of polycomplex in a block state were characterized. Due to computer processing of the polycomplex IR spectra in amide I, amide II region by the spline method, the presence of the absorption band at 1668 cm-1, related to hydrogen bonds between polymer pair, was shown. The developed hydrophobic regions in polycomplex structure in water, which additionally stabilize the polycomplex particles, were detected. The structure of such intermolecular polycomplexes is proposed.

Słowa kluczowe

EN

intermolecular polycomplex; characteristic composition; hydrogen bonds; hydrophobic regions; cooperativity

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 9
• Strony: 1347--1361
• Opis fizyczny: Bibliogr. 38 poz., rys.

Twórcy

autor

Permyakova N.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Zheltonozhskaya T.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Demchenko O.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Momot L.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Filipchenko S.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Zagdanskava N.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

autor

Syromyatnikov V.

• Kiev Taras Shevchenko National University, Faculty of Chemistry, 60 Vladimirskaya str., 01033 Kiev, Ukraine

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