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Tytuł artykułu
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Języki publikacji
Abstrakty
The reaction of ethylallyl ethylacrylate with tert-butyl hydroperoxide in the presence of molybdenum catalysts (Mo2B and Mo2B5) was studied. The general kinetic model for the process is proposed, which adequately explains the hydroperoxide consumption up to 80% conversion. The equilibrium constants of the complex formation were calculated. It was shown that Mo/B ratio in the catalyst affects the catalyst-hydroperoxide complex stability.
Słowa kluczowe
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Rocznik
Tom
Strony
1323--1332
Opis fizyczny
Bibliogr. 9 poz., rys.
Twórcy
autor
- Department of General Chemistry, National University "Lvivska Polytechnica", St. Bandera str., 12, Lviv, 79013, Ukraine
autor
- Department of General Chemistry, National University "Lvivska Polytechnica", St. Bandera str., 12, Lviv, 79013, Ukraine
autor
- Department of General Chemistry, National University "Lvivska Polytechnica", St. Bandera str., 12, Lviv, 79013, Ukraine
Bibliografia
- 1. Sheldon R.A., Aspects of Homogeneous Catalysis, Ed. Ugo R., Dordrecht-Boston-L.: D. Reidel Publ. Co., 1981. vol. 4. p. 3.
- 2. Milchert E., Chemik, 10,325 (1987).
- 3. Jorgensen K.A., Chem. Rev., 89, 431 (1989).
- 4. Sheng M.N. and Zajacek J.G., J. Org. Chem,, 35, 1839 (1970),
- 5. Frostick F.C., Phillips B. and Starcher P.S., J. Am. Chem. Soc., 81,3350 (1959).
- 6. Phillips B., Starcher P.S. and McPeek O.L., US Pat. 2969377; C.A., 55,11434 h (1961).
- 7. Trach Yu.B., Chernyak V.I, and Nikipanchuk M.V., Petroleum Chemistry, 38, 280 (1998).
- 8. Trach Yu.B., Kinetics and Catalysis, 40, 516 (1999).
- 9. Milas N.A. and Surgenor D.M., J. Am. Chem. Soc., 68, 205 (1946).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0023-0045