Dynamics of Molecular Hydrogen Exchange in Hydrogen-Bonded Systems

Bureiko, S.; Denisov, G. S.

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Tytuł artykułu

Dynamics of Molecular Hydrogen Exchange in Hydrogen-Bonded Systems

Autorzy

Bureiko S. , Denisov G. S.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The kinetics of hydrogen exchange in molecular systems with H-bonds studied by kinetic IR spectroscopy and low-temperatureNMRspectroscopy methods is critically reviewed. The experimental rate constants and activation energies obtained so far for molecules capable of forming H-bonds as both proton donors and proton acceptors are collected and analyzed from the point of view of the influence of H-bond formation ability of the molecules- partners. The evidence available testifies to a molecular mechanism of the H-exchange reactions in inert solvents and in the gas phase via the formation of cyclic, mostly bimolecular, intermediates. The different mechanisms of the molecular H-exchange process in inert media are discussed and the possible paths of experimental elucidation of reaction mechanism are offered.

Słowa kluczowe

hydrogen exchange rate constants kinetic IR spectroscopy low-temperature NMR

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2002

Tom

Vol. 76 / nr 9

Strony

1177--1190

Opis fizyczny

Bibliogr. 57 poz., rys.

Twórcy

autor

Bureiko S.

boureiko@paloma.spbu.ru

Institute of Physics, St. Petersburg State University,Ulianovskaya 1, Petrodvorets, St. Petersburg, 198504, Russia

autor

Denisov G. S.

Institute of Physics, St. Petersburg State University,Ulianovskaya 1, Petrodvorets, St. Petersburg, 198504, Russia

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0023-0032