Sulfonation of the Naphthalene Derivatives in Protic Solvent. Principles of Isomer Distribution

• Autorzy: Brzezińska E. , Kusztal D.
• Języki publikacji: EN

Abstrakty

EN

The principles of formation of mono- and disulfonation products of selected derivatives of naphthalene in protic solvents were studied. The position of electrophilic substitution was compared with: localization energies (L+) of the parent compounds; steric effect of methoxy groups; partial charges on carbon atoms in aromatic ring; dipole moment (_) and the binding energies of the products (D). These results suggest that only steric hindrance and the binding energy of the sulfonation products of naphthalene derivatives in protic solvents may be a good prognostic index for isomer distribution substitution products.

Słowa kluczowe

EN

naphthalene derivatives; sulfonation products

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 7
• Strony: 975--981
• Opis fizyczny: Bibliogr. 23 poz., rys.

Twórcy

autor

Brzezińska E.

• Department of Analytical Chemistry, Medical University of Łódź, Muszyńskiego 1, 90-151 Łódź, Poland

autor

Kusztal D.

• Department of Analytical Chemistry, Medical University of Łódź, Muszyńskiego 1, 90-151 Łódź, Poland

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