Synthesis and Characterization of Cu(ii), Co(II), Ni(II) and Zn(II) Schiff Base Complexes from 1-Amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one with Salicylaldehyde

• Autorzy: Sönmez M. , Çekerci M.
• Języki publikacji: EN

Abstrakty

EN

Cu(II), Co(II), Ni(II) and Zn(II) metal complexes of new heterocyclic Schiff base derived from 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one with salicylaldehyde have been synthesized and characterized by elemental analyses, mass, electronic, IR and 1H NMR spectra, and also by molar conductivity measurements, magnetic moment measurements and thermogravimetric analyses (TGA). It has been found that the Schiff bases behave as a neutral bidentate (NO) and tridentate (ONO) ligands forming chelates with 1:2 (metal:ligand) stoichiometry. Octahedral environment is suggested for metal complexes. The conductivity data for the Ni(II) complexes are consistent with those expected for an electrolyte.

Słowa kluczowe

EN

Schiff bases complexes; salicylaldehyde; 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 7
• Strony: 907--914
• Opis fizyczny: Bibliogr. 26 poz., rys.

Twórcy

autor

Sönmez M.

• Department of Chemistry, Faculty of Science and Arts, Yitüncü Yil University, 65080, Van, Turkey

autor

Çekerci M.

• Department of Chemistry, Faculty of Science and Arts, Firat University, 23169, Elazig, Turkey

Bibliografia

• 1. Jungreis E. and Thabet S., Chelates Anal. Chem., 2, 149 (1969).
• 2. Dubay S.D., Singh K. and Tandon J.P., Synth. React. Inorg. Met.-Org. Chem., 23, 1251 (1993).
• 3. Mohand S.A., Levina A. and Muzart J., J Chem. Res (S)., 25,2051 (1995).
• 4. Holm R.H., Everett G.W. and Chakravorty A., Prog. Inorg. Chem., 7, 83 (1966).
• 5. Hobday M.D, and Smith T.D., Coord. Chem. Rev., 9,311 (1973).
• 6. Usha A.K. and Chandra S., Synth. React. Inorg. Met.-Org. Chem., 2, 1565 (1992).
• 7. Garg B.S. and Kapur L., Inorg. Chim. Acta, 173,223 (1990).
• 8. Chohan Z.H. and Kausar S., Chem Pharm. Bull. (Japan), 41, 951 (1993).
• 9. Zishen W., Zhiping L, and Zhenhuan Y„ Transn. Met. Chem., 18, 291 (1993).
• 10. Aitural B., Akçamur Y., Saripmar E., Yildirtm I. and Kollenz G., Monatsh. Chem., 120, 1015 (1989)
• 11. Khalil S.M.E., Stefan S.L. and Bashir K.A., Synth. React. Inorg. Met.-Org. Chem., 29, 1685 (1999).
• 12. Sönmez M., Turk. J. Chem., 25, 181 (2001).
• 13. Temel H., llhan S., Şekerci M. and Ziyadanogullari R., Spectroscopy Letters, 35, (2002) (in press).
• 14. Temel H., Çakir U., Şekerci M. and Ugras H.I., Heteroatom Chem., (2002) (in press).
• 15. Temel H. and Şekerci M., Synth. React. Inorg. Met.-Org. Chem., 31, 849 (2001).
• 16. Bellamy L.J., The Infrared Spectra of Complex Molecules, Chapman and Hall, London (1978).
• 17. Lever A.B.P., Inorganic Electronic Spectroscopy, Elsevier, Amsterdam (1984).
• 18. Şekerci M. and Ta$ E., Heteroatom Chem., 11,254 (2000).
• 19. Şekerci M., Synth. React. Inorg. Met.-Org. Chem., 30, 117 (2000).
• 20. Şekerci M. and Alkan C., Synth. React. Inorg. Met.-Org. Chem., 29, 1685 (2001).
• 21. Şekerci M. and Alkan C., J. Science and Engineering of Ftrat University., 11, 119 (1999).
• 22. Şekerci M., Ph. D. Thesis, Institute of Science, University of Firat, Elazig, Turkey, 98 (1997).
• 23. Şekerci M., S. Afr. J. Chem., 52, 79 (1999).
• 24. Şekerci M., Synth. React. Inorg. Met.-Org. Chem., 29,487 (1999).
• 25. Şekerci M., Synth. React. Inorg, Met.-Org. Chem., 30, 191 (2000).
• 26. Çukurovali A., Yilmazl., Ahmedzade M. and Özmen H., Synth. React. Inorg. Met.-Org. Chem.,31,255 (2001).