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Complexes of Cadmium (II), Mercury(II) and Lead(II) with Quercetin-5'-sulfonic Acid (QSA)

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
QSA (C15H10O10S_5H2O), a ligand, which is non-toxic and well soluble in water, forms complex compounds with cations of toxic metals (Cd, Hg, Pb). New complex compounds with QSA: Cd(C15H9O10S)2_10H2O, Hg(C15H9O10S)2ź8H2O, Pb(C15H9O10S)2ź8H2O and Pb(C15H8O10S)ź4H2O have been synthesized. Some of their physicochemical properties such as UV-VIS and infrared spectra, mass spectra, thermogravimetric analysis, and solubility were studied. It was found that the obtained compounds are sparingly soluble in water, which points out that QSA could be an antidote against cadmium, lead and mercury. The structures of the obtained compounds have been proposed.
Rocznik
Strony
1777--1786
Opis fizyczny
Bibliogr. 14 poz., rys.
Twórcy
autor
  • Department of Inorganic and Analytical Chemistry, Faculty of Chemistry, University of Technology, 6 Powstanców Warszawy Ave., P.O. Box 85, 35-959 Rzeszów, Poland
autor
  • Department of Inorganic and Analytical Chemistry, Faculty of Chemistry, University of Technology, 6 Powstanców Warszawy Ave., P.O. Box 85, 35-959 Rzeszów, Poland
Bibliografia
  • 1. Senczuk W., Toxicology. Handbook for Students, Doctors and Pharmacists, PZWL, Warsaw 1994 (in Polish).
  • 2. Buionek B., Kopach M. and Novak D., Zh. Obsh. Khim., 66, 1064 (1996).
  • 3. Kopach M. and Novak D., Zh. Neorg. Khim., 25, 2692 (1980).
  • 4. Mirzaeva L.K., Makasheva I.E. and Golovkina M.T., Zh. Obsh. Khim., 47, 1428 (1977).
  • 5. Mirzaeva L.K., Makasheva I.E. and Golovkina M.T., Zh. Obsh. Khim., 52, 1631 (1982).
  • 6. Terpiłowski J., Manczyk R. and Kopacz M., Dissert. Pharm. Pharmacol., 22, 389 (1970).
  • 7. Marczenko Z. and Balcerzak M., Spectrophotometric Methods in Inorganic Analysis, PWN, Warsaw 1998 (in Polish).
  • 8. Hughes R.J., Croley T.R., Metcalfe C.D. and March R.E., Int. J. Mass Spectr., 210/211, 371 (2
  • 9. Heneczkowski M., Kopacz M., Nowak D. and Kuźniar A., Acta Pol. Pharm. - Drug Research,58, 415 (2001).
  • 10. Pusz J., Polish J. Chem., 75, 1401 (2001).
  • 11. Pusz Nitka B. and Wołowiec S., Polish J. Chem., 75, 795 (2001).
  • 12. Kopacz M., Nowak D., Kuznyar A., Woźnicka E. and Kopacz S., Russ. J. Inorg. Chem., 47,1344 (2002).
  • 13. Silverstein R.M. and Bassler G.C., Spectrometric Identification of Organic Compounds, PWN Warsaw 1970 (in Polish).
  • 14. Sekhon S.S., Kaushal G.P. and Bhatia I.S., Microchim. Acta [Wien], II, 421 (1983).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0022-0041
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