Vibrational Spectra, Phase Transition and Nonlinear Optical Properties of Anilinium Perchlorate Molecular-Ionic Solid

• Autorzy: Marchewka M. , Debrus S. , Drozd M. , Baran J. , Barnes A. J. , Xue D. , Ratajczak H.
• Języki publikacji: EN

Abstrakty

EN

Crystals of anilinium perchlorate, C6H5NH ClO 3 4 + , were obtained by slow evaporation of an aqueous solution at room temperature. Powder Kurtz-Perry measurements were performed for the title material. The efficiency of second harmonic generation was estimated relative to KDP: d = 0.21dKDP. Room temperature powder infrared and Raman measurements for the title solid and its deuterated analogue were carried out. The vibrational spectra in the regions of the internal vibrations of the ions corroborate the X-ray data (reported by Paixao et al. [1]). Differential scanning measurements performed on the powder sample indicate a first order phase transition at about 220 K.Apossible mechanism of the phase transition is suggested in relation to disorder of the hydrogen atoms on nitrogen atoms (reported in [1]). The role of the aniline molecule in the second harmonic generation is discussed.

Słowa kluczowe

EN

FTIR spectroscopy; FT-Raman spectroscopy; hydrogen bonded molecular; second harmonic generation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 11
• Strony: 1625--1636
• Opis fizyczny: Bibliogr. 48 poz., rys.

Twórcy

autor

Marchewka M.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 937, Poland

autor

Debrus S.

• Universite Pierre et Marie Curie, Laboratoire d’Optique des Solides, CNRS-UMR 7601, 4, place Jussieu, 75252 Paris Cedex 05, France

autor

Drozd M.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 937, Poland

autor

Baran J.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, 50-950 Wrocław 2, P.O. Box 937, Poland

autor

Barnes A. J.

• School of Sciences – Chemistry, University of Salford, Salford M5 4 WT, Great Britain

autor

Xue D.

• Advanced Materials Laboratory, National Institute for Materials Science, Tsukuba, Ibaraki 305-044, Japan
• School of Chemical Engineering, Dalian University of Technology, 158 Zhongshan Road, Dalian 116012, Liaoning, PR China

autor

Ratajczak H.

• Faculty of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland

Bibliografia

• 1. Paixäo J.A., Matos Beja A., Ramos Silva M., Alte da Veiga L. and Martin-Gil J., Z. Kristallogr. NCS, 214, 85 (1999).
• 2. Kotier Z., Hierle R., Josse D., Zyss J. and Masse R., J. Opt. Soc. Am. B - Opt. Phys., 9, 534 (1992).
• 3. Zyss J., Masse R., Bagieu-Beucher M. and Levy J.P., Adv Mater., 5, 120 (1993).
• 4. Horiuchi N., Lefaucheux F., Ibanez A. and Zyss J., J. Opt. Soc. Am. B - Opt. Phys., 19, 1830 (2002).
• 5. Zyss J., Nicoud J.F. and Coquillay M., J. Chem. Phys., 81, 4160 (1984).
• 6. Ledoux I., Zyss J., Siegel J.S., Brienne J. and Lehn J.-M., Chem. Phys. Lett., 172, 440 (1990).
• 7. Thalladi V.R., Brasselet S., Weiss H.-Ch., Bläser D., Katz A.K., Carrell H.L., Boese R., Zyss J., Nangia A. and Desiraju G.R., J. Am. Chem. Soc., 120, 2563 (1998).
• 8. Zyss J., Brasselet S., Thalladi V.R. and Desiraju G.R., J. Chem. Phys., 109, 658 (1998).
• 9. Thalladi V.R., Boese R., Brasselet S., Ledoux I., Zyss J., Jetti R.K.R. and Desiraju G.R., Chem. Commun., 1639(1999).
• 10. Del Zoppo M., Castiglioni C., Tommasini M., Mondini P. and Zerbi G., Synthetic Metals, 102, 1582 (1999).
• 11. Rumi M. and Zerbi G., J. Mol. Struct., 509, 11 (1999).
• 12. Del Zoppo M., Castiglioni C., Zuliani P., Razelli A., Tommasini M., Zerbi G. and Blanchard-Desce M., J. Appl. Polymer Sci., 70, 1311 (1998).
• 13. Rumi M., Zerbi G. and Mullen K., J. Chem Phys., 108, 8662 (1998).
• 14. Quinet O. and Champagne B., J. Chem Phys., 115, 6293 (2001).
• 15. Quinet O. and Champagne B., Int. J. Quantum Chem., 89, 341 (2002).
• 16. Stammler M., Bruenner R., Schmidt W. and Orcutt D., Adv. X-Ray Anal., 9, 170 (1966).
• 17. Mylrajan M. and Srinivasan T.K.K., J. Raman Spectrosc., 22, 53 (1991).
• 18. Czarnecki P., Nawrocik W., Pająk Z. and Wąsicki ].,Phys. Rev., B49, 1511 (1994).
• 19. Czarnecki P., Nawrocik W., Pająk Z. and Wąsicki J., J. Phys. Cond. Matter, 6, 4955 (1994).
• 20. Czarnecki P., Wąsicki J., Pająk Z., Goc R., Małuszyńska H. and Habrylo S., J. Mol. Struct., 404, 175 (1997).
• 21. Martin A. and Pinkerton A.A., Acta Cryst., C5I, 2174 (1995).
• 22. Drozd M. and Marchewka M.K., unpublished results.
• 23. Marchewka M.K. and Ratajczak H., unpublished results.
• 24. Rai J.N. and Maheshwari R.C., Current Science, 39, 435 (1970).
• 25. Niu Z., Dunn K.M. and Boggs J.E., Mol. Phys., 55, 421 (1985).
• 26. Akyuz S. and Davies J.E.D., J. Mol. Struct., 95, 157 (1982).
• 27. Ognyanova V., Andreev G.N., Stamboliyska B. and Juchnovski I.N., J. Mol. Struct., 513, 139 (1999).
• 28. Campagnaro G.E. and Wood J.L., J. Mol. Struct., 6, 117 (1970).
• 29. Derollez P., Bee M. and Jobie H., Spectrochim. Acta, 48A, 743 (1992).
• 30. Kozhevina L.I., Prokopenko E.B., Rybachenko V.I. and Titov E.V., Zh. Prikl. Spektr., 60, 19 (1994).
• 31. Ohashi K., Inokuchi Y., Izutsu H., Hino K., Yamamoto N., Nishi N. and Sekiya H., Chem. Phys. Lett., 323, 43 (2000).
• 32. Kurtz S.K. and Perry T.T., J. Appl. Phys., 39, 3798 (1968).
• 33. Siebert H., Z. Anorg. allg. Chem., 275, 225 (1954).
• 34. Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley, N' 1986.
• 35. Schulze H., WeinstockN., Mueller A. and Vandrish G., Spectrochim. Acta, 29A, 1705 (1973).
• 36. Videnova-Adrabiriska V., J. Mol. Struct., 237, 367 (1990).
• 37. DamakM.,KamounM., Daoud A., Romain F., Lautie A. and Novak A.,J. Mol. Struct., 130,245 (1985)
• 38. Marchewka M.K., Baran J. and Ratajczak H., Vibr. Spectr., accepted (2003).
• 39. Baran J., Marchewka M.K., Ratajczak H. and Czapla Z., J. Mol. Struct., 436-437, 281 (1997).
• 40. Herzberg G., Infrared and Raman Spectra of Polyatomic Molecules, Van Nostrand, NY, 1945.
• 41. Miller F.A., J. Raman Spectrosc., 19, 219 (1988).
• 42. Brownlee R.T.C., Cameron D.G., Topsom R.D., Katrizky A.R. and Sparrow A.J.,/ Mol. Struct., 16,36 (1973).
• 43. Marchewka M.K., Drozd M. and Pietraszko A., Mat. Sci. Eng. B, B100, 225 (2003).
• 44. Nalwa H.S., Watanabe T. and Miyata S., Nonlinear Optics of Organic Molecules and Polymers, Nalwa H. S., Miyata S., Eds., CRC Press, 1997, pp. 97-98.
• 45. Nalwa H.S., Nonlinear Optics of Organic Molecules and Polymers, Nalwa H.S. and Miyata S., Ed; CRC Press, 1997, p. 623.
• 46. Nicoud J.F. and Twieg R.J., Nonlinear Optical Properties of Organic Molecules and Crystals, Chem D.S., Zyss J., Eds., Academic Press, London, 1987, Vol. 2, p. 257.
• 47. Zyss J. and Chemla D.S., Nonlinear Optical Properties of Organic Molecules and Crystals, Chem
• D. S., Zyss J., Eds., Academic Press, London, 1987, Vol. 1, pp. 73-74.
• 48. Bosshard Ch., Sutter K., Prętre Ph., Hullinger J., Florsheimer M., Kaatz P. and Gunter P., Organic No linear Optical Materials, Gordon and Breach Publishers, 1995, pp. 37-39.