Hydroperoxide Oxidation of Benzylamines Catalyzed by Selenium Compounds

• Autorzy: Brząszcz M. , Kloc K. , Młochowski J.
• Języki publikacji: EN

Abstrakty

EN

Selenium(IV) oxide, poly(bis-1,2-phenylene) diselenide, bis[2-(N-benzisoselenazol- 3(2H)-onyl]diselenide and particularly 2-phenyl-1,2-benzisoselenazol-3(2H)-one (ebselen), were employed as the catalysts for hydrogen peroxide and t-butyl hydroperoxide oxidation of benzylamines. A reaction of primary amines proceeded via hydroxylamine and oxime, and the nitriles accompanied by imines, carboxylic acids and aldehydes were the final products. The secondary amines produced mainly the nitrones, while tetrahydroisoquinoline was dehydrogenated to isoquinoline.

Słowa kluczowe

EN

dehydrogenation; ebselen; hydroperoxides; oxidation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 11
• Strony: 1579--1586
• Opis fizyczny: Bibliogr. 31 poz., rys.

Twórcy

autor

Brząszcz M.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Kloc K.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-375 Wrocław, Poland

autor

Młochowski J.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-375 Wrocław, Poland

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