Crystal Structure and Vibrational Studies of Glycine-LiNO3 and Glycine-NaNO3 Crystals

• Autorzy: Baran J. , Drozd M. , Pietraszko A. , Trzebiatowska M. , Ratajczak H.
• Języki publikacji: EN

Abstrakty

EN

New crystal of glycine with lithium nitrate [(NN3 +CH2COO-)LiNO3; GLiN] was discovered. It belongs to the space group P1 of the triclinic system. Its structure is different from that of the glycine-NaNO3 crystal (GNaN). The Li2O6 units can be distinguished in the GLiN crystal. They have a shape of two symmetry related (through a centre of inversion) tetrahedrons with a common edge. Powder IR and FT-Raman spectra of GLiN and its deuterated analogue and of GNaN were measured and discussed with respect to the crystal structures. The splitting of some vibrations is observed, which suggests the breaking of the selection rules for the centre of inversion.

Słowa kluczowe

EN

glycine-NaNO3; glycine-LiNO3; X-ray crystal structure; IR; Raman; hydrogen bond; phase transition

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 11
• Strony: 1561--1577
• Opis fizyczny: Bibliogr. 24 poz., rys.

Twórcy

autor

Baran J.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50950 Wrocław 3, Poland

autor

Drozd M.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50950 Wrocław 3, Poland

autor

Pietraszko A.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50950 Wrocław 3, Poland

autor

Trzebiatowska M.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50950 Wrocław 3, Poland

autor

Ratajczak H.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, P.O. Box 1410, 50950 Wrocław 3, Poland

Bibliografia

• 1. Pepinsky R., Okaya Y., Eastman D.P. and Mitsui T., Phys. Rev., 107, 1538 (1957).
• 2. Pepinsky R., Vedam K. and Okaya Y., Phys. Rev., 110(6), 1309 (1958).
• 3. Pepinsky R. and Makita Y., Bull. Amer. Phys. Soc. Series II, 7, 241 (1962).
• 4. Narayan Bhat N. and Dharmaprakash S.M., J. Cryst. Growth, 235, 511 (2002).
• 5. Sheldrick G.M., SHELX-97 Programs for refinement of crystal structures. 
• 6. Krishnakumar R.V., Subha Nadhimi M., Natarajan S., Sivakumar K. and Varghese B., Acta Cryst., C57, 1149 (2001).
• 7. Perlovich G.L., Hansen L.K. and Bauer-Brandl A., J. Thermal Analysis and Calorimetry, 66, 699 (2001).
• 8. Steinback H„ J Raman Spectrosc., 5, 49 (1976).
• 9. Krishnan R.S. and Narayanan P.S., Crystallography and Crystal Perfection; Proceedings of a Symposium held in Madras 14-18 January 1963. Edited by G.N. Ramanchandran, Academic Press, London and New York, 1963, pages 329-346.
• 10. Rosado M.T., Duarte M.L.T.S. and Fausto R., Vib. Spectrosc., 16, 35 (1998).
• 11. Williams R.W., Kalasinsky V.F. and Lowrey A.H., J. Mol. Struct.(Theochem), 281, 157 (1993).
• 12. Machida K., Kagayama A., Saito Y., Kuroda Y. and Uno T„ Spectrochim. Acta, 33A, 569 (1977).
• 13. Machida K., Kagayama A. and Saito Y., J. Raman Spectrosc., 8, 133 (1979).
• 14. Machida K., Mori M., Kagayama A. and Saito Y., J. Raman Spectrosc., 9, 139 (1980).
• 15. Khanna R.K., Horak H. and Lippincott E.R., Spectrochim. Acta, 22, 1759 (1966).
• 16. Chakraborty D. and Manogaran S., Chem. Phys. Lett., 294, 56 (1998).
• 17. Alper J.S., Dothe H. and Lowe M.A., Chem. Phys., 161, 199(1992).
• 18. Kakihana M., Akiyama M., Nagaumo T. and Okamoto M., Z. Naturfosch., 43a, 774 (1988).
• 19. Pimentel G.C. and McClellan A.L., The Hydrogen Bond, Freeman and Co., San Francisco, London, 1960, page 97.
• 20. Herzberg G., Infrared and Raman Spectra of Polyatomic Molecules, D. Van Nostrand Company, Inc., NY, 1945, page 178.
• 21. Vieme R. and Cadene M., Ferroelectrics, 5,91 (1973).
• 22. Enders-Beumer A. and Harkema S., Acta Cryst., B29, 682 (1973).
• 23. Vilminot S., Anderson M.R. and Brown I.D., Acta Cryst., B29,2628 (1973).
• 24. Johansson G.B. and Lindqvist 0., Acta Cryst., B32, 412 (1976).