Spectral Features of Unconventional Hydrogen Bonds and Proton Transfer to Transition Metal Hydrides

Epstein, L.; Belkova, N. V.; Gutsul, E. I.; Shubina, E. S.

Powiadomienia systemowe

Sesja wygasła!

Artykuł - szczegóły

Tytuł artykułu

Spectral Features of Unconventional Hydrogen Bonds and Proton Transfer to Transition Metal Hydrides

Autorzy

Epstein L. , Belkova N. V. , Gutsul E. I. , Shubina E. S.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The spectral (low temperature IR, NMR, UV-Vis) changes accompanying the formation of the new unconventional hydrogen bonds (HB): to a metal atom and to a hydride ligand of transition metal hydrides, and allowing to distinguish the different ways of proton transfer via these types of H-bonds are summarized. The spectral and theoretical results show, that HB of the first type (M…HX)and of the second (MH…HX) type induce proton transfer respectively to the metal atom and to the hydride ligand, producing classical and nonclassical cationic hydrides. The spectral evidence of ion pairs formation stabilized by HB with anions is presented.

Słowa kluczowe

IR UV NMR spectra New hydrogen bonds proton transfer organometallic hydrides

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2003

Tom

Vol. 77 / nr 11

Strony

1371--1383

Opis fizyczny

Bibliogr. 40 poz., rys.

Twórcy

autor

Epstein L.

epst@ineos.ac.ru

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, V-334, 119991 Moscow, Russia

autor

Belkova N. V.

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, V-334, 119991 Moscow, Russia

autor

Gutsul E. I.

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, V-334, 119991 Moscow, Russia

autor

Shubina E. S.

A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, V-334, 119991 Moscow, Russia

Bibliografia

1. Epstein L.M. and Shubina E.S., Coord. Chern. Rew., 231, 165 (2002).
2. Shubina E.S., Belkova N.V. and Epstein L.M., J. Organomet. Chem., 536-537, 17 (1997).
3. Rivas J.C.M. and. BrammerL., Coord. Chem. Rev., 183, 43 (1999).
4. Morris R.H., in: Recent Advances in Hydride Chemistry, Elsevier, Amsterdam, 2001, p. 3.
5. Clot E., Eisenstein O., Lee D.-H. and Crabtree R.H., in: Recent Advances in Hydride Chemistry, Elsevier Amsterdam, 2001, p. 75.
6. BclkovaN.V., Epstein L.M. and Shubina E.S., in Recent Advances in Hydride Chemistry, Elsevier, Amsterdam, 2001, p. 391.
7. Vinogradova L.E., Kreindlin A.Z., Leites L.A., Chizevskii LT., Shubina E.S. and Epstein L.f Organomet. Chem. In USSR, 3, 618 (1990).
8. Shubina E.S., Krylov A.N., Kreindlin A.Z., Rybinskaya M.I. and Epstein L.M., J. Mol. Struct., 301 (1993).
9. Epstein L.M., Krylov A.N. and Shubina E.S., J. Mol. Struct., 322, 345 (1994).
10. Kazarian S.G., Hamley P.A. and PoliakoffM., J. Am. Chem. Soc., 115, 9069 (1993).
11. Kazarian S.G., Hamley P.A. and Poliakoff M., J. Chem. Soc. Chem.Commun., 995 (1992).
12. Wessel J., Lee J.C., Peris E., Yap G.P.A., Fortin J.B., Ricci J.S., Sini G., Albinati A., Koetzle T Eisenstein O., Rheingold A.L. and Crabtree R.H., Angew. Chem., Int. Ed. Eng., 34, 2507 (1995).
13. Shubina E.S., Belkova N.V., Krylov A.N., Vorontsov E.V., Epstein L.M., Gusev D.G., Niedermann and Berke H., J. Am. Chem. Soc., 118, 1105 (1996).
14. Shubina E.S., Krylov A.N., Belkova N.V., Epstein L.M., Borisov A.P. and Machaev V.D., J. Organon Chem., 493,275 (1995).
15. Albinati A., Bakhmutov V.l., Belkova N.V., Bianchini C., Epstein L.M., Rios I. de los, Gutsul E Marvelli L., Peruzzini M., Rossi R., Shubina E.S., Vorontsov E.V. and Zanobini F., Eur. J. Inorg. Chem. 1530(2002).
16. BelkovaN.V., Shubina E.S., Epstein L.M., Nefedov S.E. and Eremenko I.L., J. Organomet. Chem., 6 58 (2000).
17. Shubina E.S., Belkova N.V, Ionidis A.V., Golubev N.S, Smirnov S.N., Schah-Mohammedi P. and Epstein L.M., Russ. Chem. Bull., 44, 1349 (1997).
18. Shubina E.S., Belkova N.V., Bakhmutova E.V., Vorontsov E., Bakhmutov V.l., Ionidis A.V., Biancf
C. , Marvelli L., Peruzzini M. and Epstein L.M., Inorg. Chim. Acta, 280, 302 (1998).
19. Messmer A., Jacobsen H. and Berke H., Chem. Eur.J., 5, 11 (1999).
20. Bakhmutov V.l., Bakhmutova E.V., Belkova N.V., Bianchini C., Epstein L.M., Peruzzini M., Shub E.S., Vorontsov E.V. and Zanobini F., Can. J. Chem., 79, 479 (2001).
21. Gruendemann S., Ulrich S., Limbach H.-H., Golubev N.S., Denisov G.S., Epstein L.M., Sabo-Etienn and Chaudret B., Inorg. Chem., 38, 2550 (1999).
22. AyllonA.,Sabo-Etiennc S., Chaudret B., Ulrich S. and Limbach H.-II., Inorg. Chim. Acta, 259, 1, (1997).
23. Girling R.B., Grebenic P. and Perutz R.N., Inorg. Chem., 25, 31 (1986).
24. Ma B., Collins C.L. and Shaefer H.F., J. Am. Chem. Soc., 118, 870 (1996).
25. Gutsul E.I., Belkova N.V., Kucheryavenko M.S., Shubina E.S., Epstein L.M., Bakhmutov Perruzzini M., Bianchini C., Zanobini F., Gribanova T.N. and Minyaev R.M., Eur. J. Chem., 9, 2210 (2003).
26. Bianchini C., Peruzzini M., Polo A. and Vacca A., Gazz. Chim. Ital., 121, 543 (1991).
27. Bianchini C., Linn K., Masi D., Mealli C., Peruzzini M., Polo A., Vacca A. and Zanobini F., Im Chem., 32,2366(1993).
28. Denisov G.S., Gusakova G.S. and Smolyansky A.J., J. Mol. Struct., 15, 377 (1973).
29. Dega-Szafran Z., Grundwald-Wyspinska M. and Szafran M., Spectrochim. Acta, 47A, 543 (1991).
30. Belkova N.V., Ionidis A.V., Epstein L.M., Shubina E.S., Gruendemann St., Golubev N.S. and Limbach H. -H., Eur. J. Inorg. Chem., 7, 2163 (2001).
31. Belkova N.V., Epstein L.M., Leddos A., Maseras F. and Shubina E.S., J. Am. Chem. Soc., 125, 7 (2003).
32. Papish E.T., Rix F.C., Spetseris N., Norton J.R. and Williams R.D., J. Am. Chem. Soc., 122,2235(200
33. YuchnevichG.V., Tarakanova E.G., Maiorov V.D.and LibrovichN.B., J. Mol. Struct., 265,237(199;
34. Castaneda J.P., Denisov G.S. and Schreiber V.M., J. Mol. Struct., 560, 151 (2001).
35. Belkova N.V., Gutsul E.I., Epstein L.M., Shubina E.S., Bianchini C., Zanobini F. and Peruzzini M., unpublished observations.
36. Gutsul E.I., Belkova N.V., Babakhina G.M., Epstein L.M., Shubina E.S., Bianchini C., Peruzzini M. and Zanobini F., Rus. Chem. Bull., 52, 1014 (2003).
37. Majers I., Sawka-Dobrowolska W. and Sobczyk L., J. Mol. Struct., 416, 113 (1977).
38. Dega-Szafran Z., Sokołowska E. and Lever A.B.P., J. Mol. Struct., 565-566, 17 (2001).
39. Jia G., Ng W.S., Yao J., Lau Ch. and Chen Y., Organomet., 15, 5039 (1996).
40. Chenekey D.M. and Oldham W.J., Chem. Rev., 93, 913 (1993).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0022-0005