Equilibrium StudyofIminodi(methylenephosphonic) Acid Complexeswith Some Metal Ions

Kurzak, B.; Kamecka, A.

Artykuł - szczegóły

Tytuł artykułu

Equilibrium StudyofIminodi(methylenephosphonic) Acid Complexeswith Some Metal Ions

Autorzy

Kurzak B. , Kamecka A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

This article discusses coordination preferences of N-substituted iminodi(methylenephosphonic) acids to the different metal ions in an aqueous solution. These ligands exhibit high complexation efficiency towards divalent metal ions. This results from both dinegatively charged phosphonate groups as well as the imino nitrogen present in their structure. A significant preference for an equimolar stoichiometry has been demonstrated in these systems. The only exception is the N-2-methyltetrahydrofuryliminodi( methylenephosphonic) acid with a tetrahydrofuryl moiety, placed in the sterically favoured position that allows its oxygen atom to be an effective metal binding site. Specific interactions between metal ions and furyl oxygen results in higher binding ability of this ligand and a formation of 1:2 species. Coordination properties of iminodi- (methylenephosphonic) acids are important factors to understand the role of the ligands and metal ions in biological systems. A summary presented in this review points on the direction of the research for future work in this area, which should be developed.

Słowa kluczowe

iminodiphosponates chemistry of complex equilibria species in solution stability constants metal complexes

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2003

Tom

Vol. 77 / nr 9

Strony

1059--1077

Opis fizyczny

Twórcy

autor

Kurzak B.

Institute of Chemistry, University of Podlasie, ul. 3 Maja 54, 08-110 Siedlce, Poland

autor

Kamecka A.

Institute of Chemistry, University of Podlasie, ul. 3 Maja 54, 08-110 Siedlce, Poland

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