Interaction of the Components in Li-V-Sn System at 470 K

• Autorzy: Azarska O. , Pavlyuk V.
• Języki publikacji: EN

Abstrakty

EN

The isothermal section of the Li-V-Sn system at 470 K has been investigated by X-ray phase analysis. There is an unmixing region, which extends at ternary system to about 12 at. % of Sn. Two ternary phases Li11V3Sn4 and ~LiV2Sn and solid solutions based on the binary compounds were obtained. Crystal structures were determined for both ternary phases: Li11V3Sn4 is a superstructure to Li13Sn5 binary compound, and LiV2Sn crystallizes in a BiF3 structure type. The solubility of the third component in the binary compounds is less than 10 at. %.

Słowa kluczowe

EN

phase diagram intermetallic compound; X-ray diffraction

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 8
• Strony: 1027--1031
• Opis fizyczny: Bibliogr. 6 poz., rys.

Twórcy

autor

Azarska O.

• Ivan Franko L'viv National University, Department of Inorganic Chemistry, Kyryl and Mefodiy str. 6, 79005, L'viv, Ukraine

autor

Pavlyuk V.

• Ivan Franko L'viv National University, Department of Inorganic Chemistry, Kyryl and Mefodiy str. 6, 79005, L'viv, Ukraine

Bibliografia

• 1. Ternary Alloys: binary alloys, quaternary alloys; Evaluated constitutional data, phase diagrams, crystal structures and applications of lithium alloy system, Eds: G. Effenberg, F. Aldinger, O. Bodak, Assoc. Ed. W. Pavlyuk, VCH Verlagsgesellschaft mbH, D-69469 Weinheim, 1995, V. 14-15, 906 p.
• 2. Massalski T.B., Binary Alloys Phase Diagrams, Am. Soc. Met., 1986,1-2, 2223 p.
• 3. Basile F., Ann. Chim., 6, 241 (1971).
• 4. Wiles D.B., Sakthivel A. and Young R. A., Program DBW 3.2S for Rietveld Analysis of X-ray and Neutron Powder Diffraction Patterns, Atlanta, Georgia Institute of Technology, 1988,11 p.
• 5. Kevorkov D.G., Pavlyuk V.V. and Stepien-Damm I., Isothermal Sections of the Li-Ti-{Si,Ge} Phase Diagrams at 470 K. The 5 International School “Phase Diagram in Material Science”, Katsyvely, 23-29 September 1996, p. 63-64.
• 6. Lozova O.A., Zatorska G.M., Kevorkov D.G. and Pavlyuk V.V., Ukr. Chim. J., 67 (5), 27 (2001).