Synthesis and Reactivity of Sugar Allyltin Derivatives

• Autorzy: Jarosz S. , Szewczyk K. , Zawisza A.
• Języki publikacji: EN

Abstrakty

EN

Thermal stability of primary sugar allyltin derivatives: Sug-CH=CH-CH2SnBu3 was studied. These organometallics with a pyranose ring are stable up to at least 214°C (boiling trichlorobenzene), while those with a furanose ring undergo already at 180°C a controlled decomposition with elimination of the tributylstannyl moiety and opening of the five-membered ring. The mechanism of this process is discussed.

Słowa kluczowe

EN

sugars allyltin derivatives; rearrangement

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 8
• Strony: 985--994
• Opis fizyczny: Bibliogr. 18 poz., rys.

Twórcy

autor

Jarosz S.

• Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44, 01-224 Warszawa 42, P.O. Box 58, Poland

autor

Szewczyk K.

• Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44, 01-224 Warszawa 42, P.O. Box 58, Poland

autor

Zawisza A.

• Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44, 01-224 Warszawa 42, P.O. Box 58, Poland

Bibliografia

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