Cyclohexylethyl- and Hexamethyleneimine Nickel(II)dithiocarbamates with 1,6-Bis(diphenylphosphino)hexane

• Autorzy: Pastorek R. , Kameníček J. , Husárek J. , Pavlíček M. , Šindelář Z. , Žák Z.
• Języki publikacji: EN

Abstrakty

EN

A binuclear diamagnetic Ni(II) dithiocarbamates with 1,6-bis(diphenylphosphino)hexane (dpph) as a bidentate bridging P,P-ligand of composition [Ni2(_-dpph)(hmidtc)2X2] (hmidtc = hexamethyleneiminedithiocarbamate, dtc = S2CN-, X = Cl, Br, I, ClO4, NCS); [Ni2(_-dpph)(cetdtc)2X2] (cetdtc = cyclohexylethyldithiocarbamate, X = Cl, Br, I, NCS) and also the mononuclear diamagnetic complex [Ni(cetdtc)(dpph)]ClO4_2H2O have been synthesized. The complexes have been studied by elemental analysis, IR and UV-VIS spectroscopy, thermal analysis, magnetochemical and conductivity measurements. X-ray structural analysis was solved for the [Ni2(_-dpph)(hmidtc)2Br2]_2CHCl3 and confirmed the presence of two NiS2PBr chromophores bonded by the P-donor atoms of 1,6-bis(diphenylphosphino)hexane.

Słowa kluczowe

EN

Ni(II)dithiocarbamate; synthesis; X-ray structure; physico-chemical study; X-ray structural analysis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2003
• Tom: Vol. 77 / nr 7
• Strony: 805--812
• Opis fizyczny: Bibliogr. 17 poz., rys.

Twórcy

autor

Pastorek R.

• Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Kameníček J.

• Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Husárek J.

• Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Pavlíček M.

• Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Šindelář Z.

• Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47 Olomouc, Czech Republic

autor

Žák Z.

• Department of Inorganic Chemistry, Masaryk University, Kotlářská 2, 611 37 Brno, Czech Republic

Bibliografia

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