Hydrogen Peroxide Oxidation of N,N-Dimethylhydrazones Promoted by Selenium compounds, Titanosilicalites or Acetonitrile

Giurg, M.; Młochowski, J.; Ambrożak, A.

Artykuł - szczegóły

Tytuł artykułu

Hydrogen Peroxide Oxidation of N,N-Dimethylhydrazones Promoted by Selenium compounds, Titanosilicalites or Acetonitrile

Autorzy

Giurg M. , Młochowski J. , Ambrożak A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

Hydrogen peroxide oxidation of N,N-dimethylhydrazones 1 promoted by title reagents has been investigated. Depending on the substrate nitrile 2 and/or amide 3 accompanied with carboxylic acid 4 and parent carbonyl compounds 5 were obtained. Formation of nitriles 2 with H2O2-acetonitrile system is limited for a few more active substrates. The mechanism of the reaction, based on generated in situ peroxyiminoacetic acid, is presented. A broad spectrum of aliphatic, unsaturated and aromatic nitriles 2 was obtained by oxidation of corresponding N,N-dimethylhydrazones 1 with hydrogen peroxide in the presence of poly(bis-9,10-anthracenyl) diselenide (PADS) (7) as catalyst.

Słowa kluczowe

oxidation hydrogen peroxide diselenides hydrazones nitriles amides

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2002

Tom

Vol. 76 / nr 12

Strony

1713--1720

Opis fizyczny

Bibliogr. 26 poz., rys.

Twórcy

autor

Giurg M.

Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

autor

Młochowski J.

Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

autor

Ambrożak A.

Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, Wyb. Wyspianskiego 27, 50-370 Wrocław, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0021-0034