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Abstrakty
A series of carbon supported nickel catalysts of various metal dispersion was characterized by temperature-programmed reduction and adsorption of hydrogen, carbon monoxide and oxygen. The examinations showed that some carbon species appear on nickel surface in the course of routine purging of the catalysts from hydrogen. The species weaken the adsorption of hydrogen but does not affect the adsorption of carbon monoxide. Dispersion of nickel determined from hydrogen, carbon monoxide and oxygen adsorption was the same, which indicates the usefulness of these adsorbates for characterizing of carbon supported nickel catalysts.
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Czasopismo
Rocznik
Tom
Strony
1649--1654
Opis fizyczny
Bibliogr. 12 poz., rys.
Twórcy
autor
- Institute of Physical Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, 01-224 Warsaw, Poland, jerzy@ichf.edu.pl
Bibliografia
- 1. Zieliński J., J. Catal, 16, 157 (1982).
- 2. Zieliński J., React, Kinet. Catal. Lett., 17, 69 (1981).
- 3. Kowalczyk Z., Sentek J., Jodzis S., Diduszko R., Presz A., Tetrzyk A., Kucharski Z. and Suwalski J., Carbon, 34, 403 (1996).
- 4. Anderson R.B., The Fischer-Tropsch Synthesis, Academic Press, 1987.
- 5. MacCarty J.G. and Wise H., J. Catal., S7,406 (1979).
- 6. Shelton J.C., Patii H.R. and Blakely J.M., Surf. Set, 43,493 (1974).
- 7. Hamilton J.C. and Blakely J.M., Surf. Set, 91, 199 (1980).
- 8. Stockwell D.M., Berfucco A., Coulston G.W. and Bennett C.O., J. Catal., 113, 317 (1988).
- 9. Stuckiess IT., Al-Sarraf N., Wartnaby C. and King D.A., J. Chem. Phys., 99, 2202 (1993).
- 10. Buyanova N.E., Karnaukhov A.P., Kefeli. L.M., Ratner I.D. and Chamyavskaya O.N., Kinet. Katal., 8, 868 (1967).
- 11. Primet M., Dalmon J.A, and Martin G.A., J. Catal, 46, 25 (1977).
- 12. Rochester C.H. and Terrell R.J., J. Chem. Soc.. Farad. Trans. I, 73, 609 (1977).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0021-0025